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In the latter case, a sharp photoluminescence (PL) signal is observed. Whether the PL\u2010inactive MSCs transform to the PL\u2010active ones is unknown. We show that PL\u2010inactive CdS MSC\u2010322 transforms to PL\u2010active CdS MSC\u2010328 and MSC\u2010373 in the presence of acetic acid (HOAc). MSC\u2010322 displays a sharp absorption at \u2248322\u2005nm, whereas MSC\u2010328 and MSC\u2010373 both have broad absorptions respectively around 328 and 373\u2005nm. In a reaction of cadmium myristate and S powder in 1\u2010octadecene, MSC\u2010322 develops; with HOAc, MSC\u2010328 and MSC\u2010373 are present. We propose that the MSCs evolve from their relatively transparent precursor compounds (PCs). The PC\u2010322 to PC\u2010328 quasi\u2010isomerization involves monomer substitution, while monomer addition occurs for the PC\u2010328 to PC\u2010373 transformation. Our findings suggest that S dominates the precursor self\u2010assembly quantitatively, and ligand\u2010bonded Cd mainly controls MSC optical properties.<\/jats:p>","DOI":"10.1002\/anie.202304329","type":"journal-article","created":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T03:03:45Z","timestamp":1684206225000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Direct and Indirect Evolution of Photoluminescent Semiconductor CdS Magic\u2010Size Clusters through Their Precursor Compounds"],"prefix":"10.1002","volume":"62","author":[{"given":"Dongqing","family":"Wang","sequence":"first","affiliation":[{"name":"Engineering Research Center in Biomaterials Sichuan University  Chengdu Sichuan 610065 P. R. 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