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Primary \u03b1\u2010amino carbonyls are readily produced under mild conditions, further enabling diverse in situ functionalization reactions\u2014including peptide coupling and Pictet\u2013Spengler cyclization\u2014that capitalize on the presence of the unprotected primary amine.<\/jats:p>","DOI":"10.1002\/anie.202304990","type":"journal-article","created":{"date-parts":[[2023,4,28]],"date-time":"2023-04-28T09:34:51Z","timestamp":1682674491000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Free Amino Group Transfer via \u03b1\u2010Amination of Native Carbonyls"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8220-9187","authenticated-orcid":false,"given":"Minghao","family":"Feng","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry University of Vienna  W\u00e4hringer Stra\u00dfe 38 1090 Vienna 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