{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,19]],"date-time":"2026-10-19T23:22:14Z","timestamp":1792452134856,"version":"4.5.0"},"reference-count":49,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2023,6,20]],"date-time":"2023-06-20T00:00:00Z","timestamp":1687219200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2020YFA0710000"],"award-info":[{"award-number":["2020YFA0710000"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22122901, U19A2017, 22102054"],"award-info":[{"award-number":["22122901, U19A2017, 22102054"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,7,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Synthesis of cyclohexanone oxime via the cyclohexanone\u2010hydroxylamine process is widespread in the caprolactam industry, which is an upstream industry for nylon\u20106 production. However, there are two shortcomings in this process, harsh reaction conditions and the potential danger posed by explosive hydroxylamine. In this study, we presented a direct electrosynthesis of cyclohexanone oxime using nitrogen oxides and cyclohexanone, which eliminated the usage of hydroxylamine and demonstrated a green production of caprolactam. With the Fe electrocatalysts, a production rate of 55.9\u2005g\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    can be achieved in a flow cell with almost 100\u2009% yield of cyclohexanone oxime. The high efficiency was attributed to their ability of accumulating adsorbed hydroxylamine and cyclohexanone. This study provides a theoretical basis for electrocatalyst design for C\u2212N coupling reactions and illuminates the tantalizing possibility to upgrade the caprolactam industry towards safety and sustainability.\n                  <\/jats:p>","DOI":"10.1002\/anie.202305491","type":"journal-article","created":{"date-parts":[[2023,5,26]],"date-time":"2023-05-26T03:55:09Z","timestamp":1685073309000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":119,"title":["Electrocatalytic Synthesis of Nylon\u20106 Precursor at Almost 100\u2009% Yield"],"prefix":"10.1002","volume":"62","author":[{"given":"Yandong","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemo\/Bio-Sensing and Chemometrics College of Chemistry and Chemical Engineering Hunan University  Changsha Hunan 410082 P. R. 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