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Traditional phenolic resins are generally considered to be not degradable or recyclable. Here we report the design and synthesis of linear and network structured phenolic polymers using facile polycondensation between natural aldehyde\u2010bearing phenolic compounds and polymercaptans. Linear phenolic products are amorphous with <jats:italic>T<\/jats:italic><jats:sub>g<\/jats:sub> between \u22129\u2009\u00b0C and 12\u2009\u00b0C. Cross\u2010linked networks from vanillin and its di\u2010aldehyde derivative exhibited excellent mechanical strength between 6\u201364\u2005MPa. The connecting dithioacetals are associatively adaptable strong bonds and susceptible to degradation in oxidative conditions to regenerate vanillin. These results highlight the potential of biobased sustainable phenolic polymers with recyclability and selective degradation, as a complement to the traditional phenol\u2010formaldehyde resins.<\/jats:p>","DOI":"10.1002\/anie.202305677","type":"journal-article","created":{"date-parts":[[2023,5,19]],"date-time":"2023-05-19T14:48:35Z","timestamp":1684507715000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Thiol\u2010Aldehyde Polycondensation for Bio\u2010based Adaptable and Degradable Phenolic Polymers"],"prefix":"10.1002","volume":"62","author":[{"given":"Yu","family":"Jin","sequence":"first","affiliation":[{"name":"Anhui Agricultural University Anhui Provincial Engineering Center for High Performance Biobased Nylons  Hefei 230036 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengcheng","family":"Hu","sequence":"additional","affiliation":[{"name":"Anhui Agricultural University Anhui 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