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However, most of them rely on rare, precious metals as principal components, and integrating the functions of light absorption and catalysis into a single molecular unit based on abundant metals remains a challenge. Metal\u2010organic frameworks (MOFs), which can be regarded as intermediate compounds between molecules and inorganic solids, are potential platforms for the construction of a simple photocatalytic system composed only of Earth\u2010abundant nontoxic elements. In this work, we report that a tin\u2010based MOF enables the conversion of CO<jats:sub>2<\/jats:sub> into formic acid with a record high apparent quantum yield (9.8\u2009% at 400\u2005nm) and &gt;99\u2009% selectivity without the need for any additional photosensitizer or catalyst. 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