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Here, inspired by the transcription from duplex DNA to RNA, we synthesized Al pairs enriched low\u2010silica <jats:bold>CHA<\/jats:bold> zeolite (CHA\u2010SPAEI, Si\/Al=3.7) by using silicoaluminophosphate (SAPO) featured by strict alternation of \u2212Al\u2212O\u2212P(Si)\u2212O\u2212Al\u2212O\u2212 tetrahedra as seed. The proportion of Al pairs in CHA\u2212SPAEI is 78\u2009%, which is much higher than that in the conventional low\u2010silica <jats:bold>CHA<\/jats:bold> (CHA\u2010LS, 52\u2009%). After hydrothermal ageing at 800\u2009\u00b0C for 6\u2005h, Cu\u2010exchanged CHA\u2010SPAEI shows NO conversion above 90\u2009% within 225\u2013500\u2009\u00b0C under a gas hourly space velocity of 200,000\u2005h<jats:sup>\u22121<\/jats:sup>, which is much better than that of Cu\u2010exchanged CHA\u2010LS. The spatial close proximity of Al pairs in CHA\u2010SPAEI is confirmed by the <jats:sup>27<\/jats:sup>Al double\u2010quantum single\u2010quantum two\u2010dimensional NMR analyses. The strict \u2212P(Si)\u2212O\u2212Al\u2212O\u2212P(Si)\u2212O\u2010 sequence in the fragments from the dissolution of SAPO seed promotes the Al pairs with the \u2212Al\u2212O\u2212Si\u2212O\u2212Al\u2212O\u2212 sequence via a transcription process. The utilization of aluminophosphate\u2010based zeolites as seeds opens up a new avenue for the regulation of the Al distribution in zeolites.<\/jats:p>","DOI":"10.1002\/anie.202306174","type":"journal-article","created":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T06:29:27Z","timestamp":1684218567000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Low\u2010silica Cu\u2010CHA Zeolite Enriched with Al Pairs Transcribed from Silicoaluminophosphate Seed: Synthesis and Ammonia Selective Catalytic Reduction Performance"],"prefix":"10.1002","volume":"62","author":[{"given":"Yunzheng","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University  Changchun 130012 P. R. 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