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Commonly, spin\u2010orbit coupling can be improved by introducing heavy atoms into pure\u2010organic molecules. However, this strategy will simultaneously increase the radiative and non\u2010radiative transition rate, further resulting in dramatic decreases in the excited state lifetime and afterglow duration. Here in this work, a highly symmetric bird\u2010like structure tetraphenylene (TeP), and its three symmetrical halogenated derivatives (TeP\u2212F, TeP\u2212Cl and TeP\u2212Br) are synthesized, while their RTP properties and mechanisms are systematically investigated by both theoretical and experimental approaches. As the results, the rigid, highly twisted conformation of TeP restricts the non\u2010radiative processes of RTP and gives rise to the enhancement of electron\u2010exchange, which can contribute to the RTP radiation process. Despite the faint RTP of the bromine and chlorine\u2010substituted ones (TeP\u2212Br, TeP\u2212Cl), the fluoro\u2010substituted TeP\u2212F exhibited a long phosphorescent lifetime up to 890\u2005ms, corresponding to an extremely long RTP afterglow over 8\u2005s, which could be incorporated into the best series of non\u2010heavy\u2010atom RTP materials reported in previous literature.<\/jats:p>","DOI":"10.1002\/anie.202306475","type":"journal-article","created":{"date-parts":[[2023,6,27]],"date-time":"2023-06-27T09:48:50Z","timestamp":1687859330000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["A Heavy\u2010atom\u2010free Molecular Motif Based on Symmetric Bird\u2010like Structured Tetraphenylenes with Room\u2010Temperature Phosphorescence (RTP) Afterglow over 8\u2009s"],"prefix":"10.1002","volume":"62","author":[{"given":"Xinqi","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University Changchun 130012 (P. 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