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Isolation and crystallization was successful for the first time, and the X\u2010ray crystallographic investigation unraveled structural similarities with antimony(III)corroles. EPR experiments showed strong hyperfine interactions of the unpaired electron with the\n                    <jats:sup>121<\/jats:sup>\n                    Sb (\n                    <jats:italic>I<\/jats:italic>\n                    =5\/2) and\n                    <jats:sup>123<\/jats:sup>\n                    Sb nuclei (\n                    <jats:italic>I<\/jats:italic>\n                    =7\/2). A DFT analysis supports the description of the oxidized form as a Sb\n                    <jats:sup>III<\/jats:sup>\n                    corrole radical with less than 2\u2009% Sb\n                    <jats:sup>IV<\/jats:sup>\n                    character. In the presence of water or a fluoride source like PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , the compounds undergo a redox disproportionation to yield known antimony(III)corroles and either difluorido\u2010antimony(V)corroles, or bis\u2010\u03bc\u2010oxido\u2010di[antimony(V)corroles] via novel cationic hydroxo\u2010antimony(V) derivatives.\n                  <\/jats:p>","DOI":"10.1002\/anie.202306598","type":"journal-article","created":{"date-parts":[[2023,6,15]],"date-time":"2023-06-15T08:43:10Z","timestamp":1686818590000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Do Corroles Stabilize Tetravalent Antimony?"],"prefix":"10.1002","volume":"62","author":[{"given":"Simon","family":"Eulberg","sequence":"first","affiliation":[{"name":"Institute of Inorganic and Analytical Chemistry TU Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nina","family":"Schulze","sequence":"additional","affiliation":[{"name":"Institute of Inorganic and Analytical Chemistry TU Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jens","family":"Krumsieck","sequence":"additional","affiliation":[{"name":"Institute of Inorganic and Analytical Chemistry TU Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niels","family":"Klein","sequence":"additional","affiliation":[{"name":"Institute of Inorganic and Analytical Chemistry TU Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6807-6579","authenticated-orcid":false,"given":"Martin","family":"Br\u00f6ring","sequence":"additional","affiliation":[{"name":"Institute of Inorganic and Analytical 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