{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T17:47:57Z","timestamp":1791395277971,"version":"4.3.3"},"reference-count":114,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2023,6,20]],"date-time":"2023-06-20T00:00:00Z","timestamp":1687219200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,7,24]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The conversion of industrial exhaust gases of nitrogen oxides into high\u2010value products is significantly meaningful for global environment and human health. And green synthesis of amino acids is vital for biomedical research and sustainable development of mankind. Herein, we demonstrate an innovative approach for converting nitric oxide (NO) to a series of \u03b1\u2010amino acids (over 13 kinds) through electrosynthesis with \u03b1\u2010keto acids over self\u2010standing carbon fiber membrane with CoFe alloy. The essential leucine exhibits a high yield of 115.4\u2005\u03bcmol\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    corresponding a Faradaic efficiency of 32.4\u2009%, and gram yield of products can be obtained within 24\u2005hours in lab as well as an ultra\u2010long stability (&gt;240\u2005h) of the membrane catalyst, which could convert NO into NH\n                    <jats:sub>2<\/jats:sub>\n                    OH rapidly attacking \u03b1\u2010keto acid and subsequent hydrogenation to form amino acid. In addition, this method is also suitable for other nitrogen sources including gaseous NO\n                    <jats:sub>2<\/jats:sub>\n                    or liquidus NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and NO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    . Therefore, this work not only presents promising prospects for converting nitrogen oxides from exhaust gas and nitrate\u2010laden waste water into high\u2010value products, but also has significant implications for synthetizing amino acids in biomedical and catalytic science.\n                  <\/jats:p>","DOI":"10.1002\/anie.202306726","type":"journal-article","created":{"date-parts":[[2023,5,31]],"date-time":"2023-05-31T01:08:37Z","timestamp":1685495317000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":142,"title":["Electrosynthesis of \u03b1\u2010Amino Acids from NO and other NO\n                    <sub>\n                      <i>x<\/i>\n                    <\/sub>\n                    species over CoFe alloy\u2010decorated Self\u2010standing Carbon Fiber Membranes"],"prefix":"10.1002","volume":"62","author":[{"given":"Jiahui","family":"Xian","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioinorganic and 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