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Herein, we report a conceptually different approach toward highly functionalized organoborane synthesis by using recoverable ultrathin cadmium sulfide (CdS) nanosheets as a heterogeneous photocatalyst, and a general and mild borylation platform that enables regioselective borylation of a wide variety of alkenes (arylethenes, trifluoromethylalkenes,\n                    <jats:italic>\u03b1<\/jats:italic>\n                    ,\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010unsaturated carbonyl compounds and nitriles), alkynes, imines and electron\u2010poor aromatic rings with NHC\u2010borane as boryl radical precursor. Mechanistic studies and density functional theory (DFT) calculations reveal that both photogenerated electrons and holes on the CdS fully perform their own roles, thereby resulting in enhancement of photocatalytic activity and stability of CdS.\n                  <\/jats:p>","DOI":"10.1002\/anie.202306846","type":"journal-article","created":{"date-parts":[[2023,8,9]],"date-time":"2023-08-09T10:25:57Z","timestamp":1691576757000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Facile Borylation of Alkenes, Alkynes, Imines, Arenes and Heteroarenes with\n                    <i>N<\/i>\n                    \u2010Heterocyclic Carbene\u2010Boranes and a Heterogeneous Semiconductor Photocatalyst"],"prefix":"10.1002","volume":"62","author":[{"given":"Fukai","family":"Xie","sequence":"first","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhan","family":"Mao","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dennis P.","family":"Curran","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Pittsburgh  Pittsburgh PA 15208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongliang","family":"Liang","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9098-5215","authenticated-orcid":false,"given":"Wen","family":"Dai","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,8,18]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00385B"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911108"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.05.008"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC04245G"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102717"},{"key":"e_1_2_7_6_1","first-page":"13","author":"Vallet A.-L.","year":"2014","journal-title":"Sci. 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