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Here, we report an appealing layout of advancing chlorine\u2010functionalized eutectic (Cl\u2010FE) electrolytes via exploiting Cl anion\u2010induced eutectic interaction with Zn acetate solutions. This novel eutectic liquid shows high affinity to collaborate with 1,3\u2010dioxolane (DOL) and is prone to constitute Cl\u2010FE\/DOL\u2010based electrolytes with a unique inner\/outer eutectic solvation sheath for the better regulation of Zn\u2010solvating neighboring and reconstruction of H\u2010bonding. The side reactions are effectively restricted on Zn anodes and a high Coulombic efficiency of 99.5\u2009% can be achieved over 1000\u2005cycles at \u221220\u2009\u00b0C with Zn\/\/Cu setups. By prototyping scale\u2010up Zn\u2010ion pouch cells using the optimal eutectic liquid of 3ZnOAc\n                    <jats:sub>1.2<\/jats:sub>\n                    Cl\n                    <jats:sub>1.8<\/jats:sub>\n                    \u2010DOL, we obtain improved electrochemical properties at \u221220\u2009\u00b0C with a high capacitance of 203.9\u2005F\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.02\u2005A\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    in a range of 0.20\u20131.90\u2005V and long\u2010term cycling ability with 95.3\u2009% capacitance retention at 0.2\u2005A\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    over 3,000\u2005cycles. Overall, the proposal of ideal Cl\u2010FE\/DOL\u2010based electrolytes guides the design of sub\u2010zero and endurable aqueous ZEES devices and beyond.\n                  <\/jats:p>","DOI":"10.1002\/anie.202307475","type":"journal-article","created":{"date-parts":[[2023,6,15]],"date-time":"2023-06-15T12:22:31Z","timestamp":1686831751000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":46,"title":["Ultra\u2010stable Zinc Metal Anodes at \u221220\u2009\u00b0C through Eutectic Solvation Sheath in Chlorine\u2010functionalized Eutectic Electrolytes with 1,3\u2010Dioxolane"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8155-8687","authenticated-orcid":false,"given":"Xuejun","family":"Lu","sequence":"first","affiliation":[{"name":"School of Engineering, Faculty of Applied Science University of British Columbia  Kelowna BC\u2009V1V\u20091V7 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