{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T18:40:42Z","timestamp":1788460842893,"version":"build-2803163510"},"reference-count":77,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2023,9,4]],"date-time":"2023-09-04T00:00:00Z","timestamp":1693785600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["2019\/34\/E\/ST5\/00148"],"award-info":[{"award-number":["2019\/34\/E\/ST5\/00148"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,10,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Switching of multiple physical properties by external stimuli in dynamic materials enables applications in, e.g., smart sensors, biomedical tools, as well as data\u2010storage devices. Among stimuli\u2010responsive materials, inorganic\u2010organic molecular hybrids exhibiting thermal order\u2010disorder phase transitions were tested as promising molecular switches of electrical characteristics, including dielectric constant. We aimed at broadening the multifunctional potential of such hybrid materials towards the switching of not only electrical but also other physical properties, e.g., light emission. We report two ionic salts based on luminescent tetracyanidonitridorhenate(V) anions bearing two different diamine ligands, 1,2\u2010diaminoethane (\n                    <jats:bold>1<\/jats:bold>\n                    ) and 1,3\u2010diaminopropane (\n                    <jats:bold>2<\/jats:bold>\n                    ), both crystallizing with polar\n                    <jats:italic>N<\/jats:italic>\n                    \u2010methyl\u2010dabconium cations. They exhibit an order\u2010disorder phase transition related to the heating\u2010induced turning\u2010on of the rotation of polar cations. This leads to a unique synchronous switching of the dielectric constant as well as metal\u2010complex\u2010centered photoluminescence, as demonstrated by changes in, e.g., emission lifetime. The roles of organic cations, non\u2010trivial Re(V) complexes, and their interaction in achieving the coupled thermal switching of electrical and optical properties are discussed utilizing experimental and theoretical approaches.\n                  <\/jats:p>","DOI":"10.1002\/anie.202308284","type":"journal-article","created":{"date-parts":[[2023,8,24]],"date-time":"2023-08-24T10:59:47Z","timestamp":1692874787000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Synchronous Switching of Dielectric Constant and Photoluminescence in Cyanidonitridorhenate\u2010Based Crystals"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8102-1801","authenticated-orcid":false,"given":"Michal","family":"Liberka","sequence":"first","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa 2 30-387 Krak\u00f3w Poland"},{"name":"Doctoral School of Exact and Natural Sciences Jagiellonian University  \u0141ojasiewicza 11 30-348 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9789-8173","authenticated-orcid":false,"given":"Mikolaj","family":"Zychowicz","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa 2 30-387 Krak\u00f3w Poland"},{"name":"Doctoral School of Exact and Natural Sciences Jagiellonian University  \u0141ojasiewicza 11 30-348 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3859-6172","authenticated-orcid":false,"given":"James","family":"Hooper","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa 2 30-387 Krak\u00f3w Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5946-944X","authenticated-orcid":false,"given":"Koji","family":"Nakabayashi","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo  7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9359-5928","authenticated-orcid":false,"given":"Shin\u2010ichi","family":"Ohkoshi","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo  7-3-1 Hongo Bunkyo-ku, Tokyo 113-0033 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1669-9835","authenticated-orcid":false,"given":"Szymon","family":"Chorazy","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jagiellonian University  Gronostajowa 2 30-387 Krak\u00f3w 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