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Each panel usually exhibits planar chirality and prefers chirality\u2010aligned states. Because of this feature, pillar[\n                    <jats:italic>n<\/jats:italic>\n                    ]arenes are attractive scaffolds for chiroptical materials that are easy to prepare and optically resolve and show intense circular dichroism (CD) signals. In addition, rotation of the panels endows the chirality of pillar[\n                    <jats:italic>n<\/jats:italic>\n                    ]arenes with a dynamic nature. The chirality in tubular oligomers and supramolecular assemblies sometimes show time\u2010 and procedure\u2010dependent alignment phenomena. Furthermore, the CD signals of some pillar[\n                    <jats:italic>n<\/jats:italic>\n                    ]arenes respond to the addition of chiral guests when their dynamic chirality is coupled with host\u2013guest properties. By using diastereomeric pillar[\n                    <jats:italic>n<\/jats:italic>\n                    ]arenes with additional chiral structures, the response can also be caused by achiral guests and changes of the environment, providing molecular sensors.\n                  <\/jats:p>","DOI":"10.1002\/anie.202308316","type":"journal-article","created":{"date-parts":[[2023,7,30]],"date-time":"2023-07-30T22:39:43Z","timestamp":1690756783000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":74,"title":["Alignment and Dynamic Inversion of Planar Chirality in Pillar[\n                    <i>n<\/i>\n                    ]arenes"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5348-5521","authenticated-orcid":false,"given":"Kenichi","family":"Kato","sequence":"first","affiliation":[{"name":"Department of Synthetic Chemistry and Biological Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo-ku  Kyoto 615-8510 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2261-409X","authenticated-orcid":false,"given":"Shixin","family":"Fa","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Northwestern Polytechnical University Xi'an  Shaanxi 710072 P. 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