{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T01:47:06Z","timestamp":1792115226048,"version":"4.4.0"},"reference-count":52,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2023,7,28]],"date-time":"2023-07-28T00:00:00Z","timestamp":1690502400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,9,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Artificial H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    photosynthesis by covalent organic frameworks (COFs) photocatalysts is promising for wastewater treatment. The effect of linkage chemistry of COFs as functional basis to photoelectrochemical properties and photocatalysis remains a significant challenge. In this study, three kinds of azoles\u2010linked COFs including thiazole\u2010linked TZ\u2010COF, oxazole\u2010linked OZ\u2010COF and imidazole\u2010linked IZ\u2010COF were successfully synthesized. More accessible channels of charge transfer were constructed in TZ\u2010COF via the donor\u2010\u03c0\u2010acceptor structure between thiazole linkage and pyrene linker, leading to efficient suppression of photoexcited charge recombination. Density functional theory calculations support the experimental studies, demonstrating that the thiazole linkage is more favorable for the formation of *O\n                    <jats:sub>2<\/jats:sub>\n                    intermediate in H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production than that of the oxazole and imidazole linkages. The real active sites in COFs located at the benzene ring fragment between pyrene unit and azole linkage.\n                  <\/jats:p>","DOI":"10.1002\/anie.202309480","type":"journal-article","created":{"date-parts":[[2023,7,18]],"date-time":"2023-07-18T08:25:53Z","timestamp":1689668753000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":356,"title":["Linkage Microenvironment of Azoles\u2010Related Covalent Organic Frameworks Precisely Regulates Photocatalytic Generation of Hydrogen Peroxide"],"prefix":"10.1002","volume":"62","author":[{"given":"Yi","family":"Mou","sequence":"first","affiliation":[{"name":"College of Environmental Science and Engineering Key Laboratory of Environmental Biology and Pollution Control Hunan University  Changsha 410082 P. R. 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