{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:28:42Z","timestamp":1786976922905,"version":"build-2736575974"},"reference-count":22,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2023,8,17]],"date-time":"2023-08-17T00:00:00Z","timestamp":1692230400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22241502, 22035004"],"award-info":[{"award-number":["22241502, 22035004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Two\u2010dimensional (2D) AIE\u2010inorganic nanocomposites exhibit high stability and high fluorescence activity. However, limited by the types and properties of 2D inorganic materials, it's challenging to realize complex structures and functions. We designed a quaternary ammonium\u2010type AIE ligand, TPECholine. We chose TPECholine and POM clusters as building blocks and synthesized a series of single\u2010layer nanosheets (SLNSs) by assembling LnW\n                    <jats:sub>10<\/jats:sub>\n                    or P\n                    <jats:sub>2<\/jats:sub>\n                    W\n                    <jats:sub>18<\/jats:sub>\n                    POM clusters with TPECholine. By regulating the types of POM clusters and ligands, the morphology and fluorescence intensity of the SLNSs can be finely tuned. Due to the restriction of the intramolecular motions of AIEgens by the SLNSs, nanosheets can exhibit promoted quantum yield (up to 76\u2009%). In addition, thanks to the sub\u2010nanometric sizes and excess surface charges, SLNSs exhibit excellent solvent compatibility, including water, chloroform, ethanol, etc. And the nanosheets showed high fluorescence intensity in these solvents.\n                  <\/jats:p>","DOI":"10.1002\/anie.202310018","type":"journal-article","created":{"date-parts":[[2023,8,8]],"date-time":"2023-08-08T06:17:58Z","timestamp":1691475478000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Tunable Fluorescence from 2D Assemblies of LnW\n                    <sub>10<\/sub>\n                    and P\n                    <sub>2<\/sub>\n                    W\n                    <sub>18<\/sub>\n                    Polyoxometalates Clusters with Quaternary Ammonium\u2010type AIEgens"],"prefix":"10.1002","volume":"62","author":[{"given":"Shujian","family":"Rong","sequence":"first","affiliation":[{"name":"Key Lab of Organic Optoelectronics and Molecular Engineering Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengshi","family":"Wang","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Bioorganic Phosphorus Chemistry &amp; Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8066-4450","authenticated-orcid":false,"given":"Xun","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Lab of Organic Optoelectronics and Molecular Engineering Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,8,17]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10150"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201707210"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-022-2215-1"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00263"},{"key":"e_1_2_3_6_1","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-020-2997-0"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202100780"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201912322"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-021-1652-2"},{"key":"e_1_2_3_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY01167G"},{"key":"e_1_2_3_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403811"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TC00736D"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms11811"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc16218k"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc45041d"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature13951"},{"key":"e_1_2_3_18_1","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE03749A"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4208"},{"key":"e_1_2_3_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217764"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC07216J"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202310018","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,14]],"date-time":"2023-09-14T12:56:10Z","timestamp":1694696170000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202310018"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,17]]},"references-count":22,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2023,9,18]]}},"alternative-id":["10.1002\/anie.202310018"],"URL":"https:\/\/doi.org\/10.1002\/anie.202310018","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,17]]},"assertion":[{"value":"2023-07-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-08-17","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202310018"}}