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Herein, we report the solvent\u2010controlled rhodium\u2010catalyzed tunable arylation of 1\u2010bromo\u20102,2\u2010difluoroethylene. The selection of the reaction solvents provides switchable defluorinated or debrominated arylation from readily available feedstock resources (both arylboronic acids\/esters and 1\u2010bromo\u20102,2\u2010difluoroethylene are commercially available). This switch is feasible because of the difference in coordination ability between the solvent (CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> or CH<jats:sub>3<\/jats:sub>CN) and the rhodium center, resulting in different olefin insertion. This protocol allows the convenient synthesis of monofluoroalkenes and <jats:italic>gem\u2010<\/jats:italic>difluoroalkenes, both of which are important scaffolds in the fields of medicine and materials. Moreover, this newly developed solvent\u2010regulated reaction system can be applied to the site\u2010selective dechlorinated arylation of trichloroethylene. 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