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We developed a catalytic system comprised of Ru\u2010ReO\n                    <jats:sub>x<\/jats:sub>\n                    \/SiO\n                    <jats:sub>2<\/jats:sub>\n                    +HZSM\u20105 for direct HDO of polycarbonate (PC), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyphenylene oxide (PPO), and their mixtures, to cycloalkanes as LOHCs, with high yields up to 99\u2009%, under mild reaction conditions. The theoretical hydrogen storage capacity reaches ca. 5.74\u2005wt%. The reaction pathway involves depolymerization of PC into C\n                    <jats:sub>15<\/jats:sub>\n                    aromatics and C\n                    <jats:sub>15<\/jats:sub>\n                    monophenols by direct hydrogenolysis of the C\u2212O bond between the benzene ring and ester group, and subsequent parallel hydrogenation of C\n                    <jats:sub>15<\/jats:sub>\n                    aromatics and HDO of C\n                    <jats:sub>15<\/jats:sub>\n                    monophenols. HDO of cyclic alcohol is the rate\u2010determining step. The active site is Ru metallic nanoparticles with partially covered ReO\n                    <jats:sub>x<\/jats:sub>\n                    species. The excellent performance is attributed to the synergetic effect of oxophilic ReO\n                    <jats:sub>x<\/jats:sub>\n                    species and Ru metallic sites for C\u2212O hydrogenolysis and hydrogenation, and the promotion effect of HZSM\u20105 for dehydration of cyclic alcohol. The highly efficient and stable dehydrogenation of cycloalkanes over Pt\/\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    confirms that HDO products can act as LOHCs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202310505","type":"journal-article","created":{"date-parts":[[2023,8,3]],"date-time":"2023-08-03T05:04:11Z","timestamp":1691039051000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":81,"title":["Hydrodeoxygenation of Oxygen\u2010Containing Aromatic Plastic Wastes to Liquid Organic Hydrogen Carriers"],"prefix":"10.1002","volume":"62","author":[{"given":"Junde","family":"Wei","sequence":"first","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengmeng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Tohoku University  Aoba 6\u20136-07, Aoba, Aramaki, Aoba-ku Sendai Miyagi 980-8579 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jieyi","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keiichi","family":"Tomishige","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Tohoku University  Aoba 6\u20136-07, Aoba, Aramaki, Aoba-ku Sendai Miyagi 980-8579 Japan"},{"name":"Advanced Institute for Materials Research (WPI-AIMR) Tohoku University  2-1-1 Katahira, Aoba-ku Sendai Miyagi 980-8577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9735-3491","authenticated-orcid":false,"given":"Sibao","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"},{"name":"Haihe Lab of Sustainable Chemical Transformations  Tianjin 300192 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhu","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology  Tianjin 300072 China"},{"name":"Haihe Lab of Sustainable Chemical Transformations  Tianjin 300192 China"},{"name":"Zhejiang Institute of Tianjin University  Ningbo Zhejiang 315201 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,8,17]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"D. 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