{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:16:30Z","timestamp":1791728190182,"version":"4.3.4"},"reference-count":72,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2023,10,31]],"date-time":"2023-10-31T00:00:00Z","timestamp":1698710400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2023,12,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The need of carbon sources for the chemical industry, alternative to fossil sources, has pointed to CO<jats:sub>2<\/jats:sub> as a possible feedstock. While CO<jats:sub>2<\/jats:sub> electroreduction (CO<jats:sub>2<\/jats:sub>R) allows production of interesting organic compounds, it suffers from large carbon losses, mainly due to carbonate formation. This is why, quite recently, tandem CO<jats:sub>2<\/jats:sub>R, a two\u2010step process, with first CO<jats:sub>2<\/jats:sub>R to CO using a solid oxide electrolysis cell followed by CO electroreduction (COR), has been considered, since no carbon is lost as carbonate in either step. Here we report a novel copper\u2010based catalyst, silver\u2010doped copper nitride, with record selectivity for formation of propanol (Faradaic efficiency: 45\u2009%), an industrially relevant compound, from CO electroreduction in gas\u2010fed flow cells. Selective propanol formation occurs at metallic copper atoms derived from copper nitride and is promoted by silver doping as shown experimentally and computationally. In addition, the selectivity for C<jats:sub>2+<\/jats:sub> liquid products (Faradaic efficiency: 80\u2009%) is among the highest reported so far. These findings open new perspectives regarding the design of catalysts for production of C<jats:sub>3<\/jats:sub> compounds from CO<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.202310788","type":"journal-article","created":{"date-parts":[[2023,10,9]],"date-time":"2023-10-09T18:34:09Z","timestamp":1696876449000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Silver and Copper Nitride Cooperate for CO Electroreduction to Propanol"],"prefix":"10.1002","volume":"62","author":[{"given":"Hong","family":"Phong Duong","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie des Processus Biologiques CNRS UMR 8229 Coll\u00e8ge de France Sorbonne Universit\u00e9  11 Place Marcelin Berthelot 75231 Paris Cedex 05 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jose Guillermo","family":"Rivera de la Cruz","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Processus Biologiques CNRS UMR 8229 Coll\u00e8ge de France Sorbonne Universit\u00e9  11 Place Marcelin Berthelot 75231 Paris Cedex 05 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ngoc\u2010Huan","family":"Tran","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Processus Biologiques CNRS UMR 8229 Coll\u00e8ge de France Sorbonne Universit\u00e9  11 Place Marcelin Berthelot 75231 Paris Cedex 05 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacques","family":"Louis","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie du Solide et Energie CNRS UMR 8260 Coll\u00e8ge de France Sorbonne Universit\u00e9  1 Place Marcelin Berthelot 75231 Paris Cedex 05 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandrine","family":"Zanna","sequence":"additional","affiliation":[{"name":"Chimie ParisTech PSL Research University CNRS Institut de Recherche de Chimie Paris (IRCP)  11 rue Pierre et Marie Curie 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Portehault","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 CNRS Laboratoire de Chimie de la Mati\u00e8re Condens\u00e9e de Paris (CMCP)  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Zitolo","sequence":"additional","affiliation":[{"name":"Synchrotron SOLEIL  L'Orme des Merisiers Saint-Aubin BP 48 91192 Gif-sur-Yvette France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Walls","sequence":"additional","affiliation":[{"name":"CNRS UMR 8502 Universit\u00e9 Paris-Saclay Laboratoire de Physique des Solides  F-91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Deizi Vanessa","family":"Peron","sequence":"additional","affiliation":[{"name":"Total Research and Technology, Refining and Chemicals Division CO<sub>2<\/sub> Conversion  Feluy 7181 Seneffe Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Moritz W.","family":"Schreiber","sequence":"additional","affiliation":[{"name":"Total Research and Technology, Refining and Chemicals Division CO<sub>2<\/sub> Conversion  Feluy 7181 Seneffe Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolas","family":"Menguy","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 UMR CNRS 7590 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie  75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8016-4747","authenticated-orcid":false,"given":"Marc","family":"Fontecave","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des Processus Biologiques CNRS UMR 8229 Coll\u00e8ge de France Sorbonne Universit\u00e9  11 Place Marcelin Berthelot 75231 Paris Cedex 05 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,10,31]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav3506"},{"key":"e_1_2_8_4_1","unstructured":"\u00a0"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00973-9"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0388-2"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00010"},{"key":"e_1_2_8_8_1","unstructured":"\u00a0"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.02.008"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE00047G"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19135-8"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2019.03.142"},{"key":"e_1_2_8_13_1","unstructured":"\u00a0"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg6582"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00761-y"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00901"},{"key":"e_1_2_8_17_1","unstructured":"\u00a0"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.01.007"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02633"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910662"},{"key":"e_1_2_8_21_1","unstructured":"\u00a0"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c06068"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03143"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13190-6"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00967-7"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0380-x"},{"key":"e_1_2_8_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01124"},{"key":"e_1_2_8_28_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13249"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0301-z"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0133-2"},{"key":"e_1_2_8_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.12.011"},{"key":"e_1_2_8_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11790"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.10.007"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.7b03514"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jascer.2014.08.007"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00190"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29140-8"},{"key":"e_1_2_8_38_1","unstructured":"\u00a0"},{"key":"e_1_2_8_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06765"},{"key":"e_1_2_8_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE01341E"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c09128"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1702405114"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE02826F"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c07553"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36411-5"},{"key":"e_1_2_8_46_1","unstructured":"\u00a0"},{"key":"e_1_2_8_47_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31427-9"},{"key":"e_1_2_8_48_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0139-9"},{"key":"e_1_2_8_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02610"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2214175120"},{"key":"e_1_2_8_50_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02945"},{"key":"e_1_2_8_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE01501E"},{"key":"e_1_2_8_52_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.07.009"},{"key":"e_1_2_8_53_1","unstructured":"\u00a0"},{"key":"e_1_2_8_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c00761"},{"key":"e_1_2_8_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.9b03324"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06820"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002382"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201901309"},{"key":"e_1_2_8_59_1","unstructured":"\u00a0"},{"key":"e_1_2_8_60_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-20615-0"},{"key":"e_1_2_8_61_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0201-7"},{"key":"e_1_2_8_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.6b02273"},{"key":"e_1_2_8_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00022"},{"key":"e_1_2_8_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b06227"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00042J"},{"key":"e_1_2_8_66_1","unstructured":"\u00a0"},{"key":"e_1_2_8_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01485H"},{"key":"e_1_2_8_68_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE03838A"},{"key":"e_1_2_8_69_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0269-8"},{"key":"e_1_2_8_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b11390"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY01423D"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202310788","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,12,13]],"date-time":"2023-12-13T03:01:57Z","timestamp":1702436517000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202310788"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,10,31]]},"references-count":72,"journal-issue":{"issue":"49","published-print":{"date-parts":[[2023,12,4]]}},"alternative-id":["10.1002\/anie.202310788"],"URL":"https:\/\/doi.org\/10.1002\/anie.202310788","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,10,31]]},"assertion":[{"value":"2023-07-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-10-31","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202310788"}}