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Starting with a short summary of the advantages of metal\u2013organic frameworks (MOFs) as catalysts in liquid\u2010phase reactions, the present article highlights the opportunities that MOFs may offer also for some gas\u2010phase reactions, particularly for the selective CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH. It is commented that there is a temperature compatibility window that combines the thermal stability of some MOFs with the temperature required in the CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH that frequently ranges from 250 to 300\u2009\u00b0C. The existing literature in this area is briefly organized according to the role of MOF as providing the active sites or as support of active metal nanoparticles (NPs). Emphasis is made to show how the flexibility in design and synthesis of MOFs can be used to enhance the catalytic activity by adjusting the composition of the nodes and the structure of the linkers. The influence of structural defects and material crystallinity, as well as the role that should play theoretical calculations in models have also been highlighted.\n                  <\/jats:p>","DOI":"10.1002\/anie.202311241","type":"journal-article","created":{"date-parts":[[2023,10,10]],"date-time":"2023-10-10T11:45:09Z","timestamp":1696938309000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":59,"title":["Selective Gas\u2010Phase Hydrogenation of CO\n                    <sub>2<\/sub>\n                    to Methanol Catalysed by Metal\u2010Organic Frameworks"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0991-6608","authenticated-orcid":false,"given":"Amarajothi","family":"Dhakshinamoorthy","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n Valencia 46022 Spain"},{"name":"School of Chemistry Madurai Kamaraj University  Madurai 625021 Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8423-0759","authenticated-orcid":false,"given":"Sergio","family":"Naval\u00f3n","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n Valencia 46022 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9205-2278","authenticated-orcid":false,"given":"Ana","family":"Primo","sequence":"additional","affiliation":[{"name":"Instituto Universitario de Tecnolog\u00eda Qu\u00edmica, CSIC-UPV Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n Valencia 46022 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9664-493X","authenticated-orcid":false,"given":"Hermenegildo","family":"Garc\u00eda","sequence":"additional","affiliation":[{"name":"Instituto Universitario de Tecnolog\u00eda Qu\u00edmica, CSIC-UPV Universitat Polit\u00e8cnica de Val\u00e8ncia  Camino de Vera s\/n Valencia 46022 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