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We report here on the hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    in water on ZnO\u2010supported CuAu nanoalloys, based on \u22647\u2005mol\u2009% Au. Cu\n                    <jats:sub>x<\/jats:sub>\n                    Au\n                    <jats:sub>y<\/jats:sub>\n                    \/ZnO catalysts were characterized using\n                    <jats:sup>197<\/jats:sup>\n                    Au M\u00f6ssbauer, in situ X\u2010ray absorption (Au L\n                    <jats:sub>III<\/jats:sub>\n                    \u2010 and Cu K\u2010edges), and ambient pressure X\u2010ray photoelectron (APXP) spectroscopic methods together with X\u2010ray diffraction and high\u2010resolution electron microscopy. At 200\u2009\u00b0C, the conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    showed a significant increase by 34\u2005times (from 0.1 to 3.4\u2009%) upon increasing Cu\n                    <jats:sub>93<\/jats:sub>\n                    Au\n                    <jats:sub>7<\/jats:sub>\n                    loading from 1 to 10\u2005wt\u2009%, while maintaining methanol selectivity at 100\u2009%. Limited CO selectivity (4\u20136\u2009%) was observed upon increasing temperature up to 240\u2009\u00b0C but associated with a \u22483\u2010fold increase in CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion. Based on APXPS during CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation in an H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010rich mixture, Cu segregates preferentially to the surface in a mainly metallic state, while slightly charged Au submerges deeper into the subsurface region. These results and detailed structural analyses are topics of the present contribution.\n                  <\/jats:p>","DOI":"10.1002\/anie.202311340","type":"journal-article","created":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T14:38:39Z","timestamp":1697726319000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Low\u2010Temperature Hydrogenation of CO\n                    <sub>2<\/sub>\n                    to Methanol in Water on ZnO\u2010Supported CuAu Nanoalloys"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7194-6325","authenticated-orcid":false,"given":"Jawaher","family":"Mosrati","sequence":"first","affiliation":[{"name":"Leibniz Institute for Catalysis (LIKAT Rostock)  18059 Rostock 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