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Here, different from traditional zeolite\u2010seeded methods that generally produced isolated mesopores in zeolites, nanosized amorphous protozeolites with embryo structure of zeolites were used as seeds for the construction of single\u2010crystalline hierarchical ZSM\u20105 zeolites with intrapenetrated mesopores (mesopore volume of 0.51\u2005cm<jats:sup>3<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>) and highly complete framework. In this strategy, in contrast to the conventional synthesis, only a small amount of organic structure directing agents and a low crystallization temperature were adopted to promise the protozeolites as the dominant growth directing sites to induce crystallization. The protozeolite nanoseeds provided abundant nucleation sites for surrounding precursors to be crystallized, followed by oriented coalescence of crystallites resulting in the formation of intrapenetrated mesopores. The as\u2010prepared hierarchical ZSM\u20105 zeolites exhibited ultra\u2010long lifetime of 443.9\u2005hours and a high propylene selectivity of 47.92\u2009% at a WHSV of 2\u2005h<jats:sup>\u22121<\/jats:sup> in the methanol\u2010to\u2010propylene reaction. This work provides a facile protozeolite\u2010seeded strategy for the synthesis of intrapenetrated hierarchical zeolites that are highly effective for catalytic applications.<\/jats:p>","DOI":"10.1002\/anie.202312131","type":"journal-article","created":{"date-parts":[[2023,10,11]],"date-time":"2023-10-11T17:10:49Z","timestamp":1697044249000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Constructing Intrapenetrated Hierarchical Zeolites with Highly Complete Framework via Protozeolite Seeding"],"prefix":"10.1002","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2679-1168","authenticated-orcid":false,"given":"Yinghao","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry Jilin University  Qianjin Street 2699 Changchun 130012 P. R. 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