{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T20:34:40Z","timestamp":1789158880549,"version":"build-2803163510"},"reference-count":46,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2023,11,28]],"date-time":"2023-11-28T00:00:00Z","timestamp":1701129600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22075187"],"award-info":[{"award-number":["22075187"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,1,22]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Currently, purely organic compounds showing ambient phosphorescence with high efficiency (\n                    <jats:italic>\u03a6<\/jats:italic>\n                    <jats:sub>P<\/jats:sub>\n                    ) and ultra\u2010long lifetime (\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>P<\/jats:sub>\n                    ) are quite rare and often need to be achieved in hydrophilic poly(vinyl alcohol)\u2010based hosts. This severely limits their applications. Here, we provide a solution to this issue by constructing an\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010linked donor\u2010acceptor (D\u2212A) dyad whose D moiety has not only a long\u2010lived T\n                    <jats:sub>1<\/jats:sub>\n                    state to achieve a long\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>P<\/jats:sub>\n                    , but also a T\n                    <jats:sub>n<\/jats:sub>\n                    state that is close to the S\n                    <jats:sub>1<\/jats:sub>\n                    state of the dyad to trigger effective spin\u2010orbit charge transfer intersystem crossing (SOCT\u2010ISC). The rationality of this strategy was validated by a new phosphor OF\u2010BCz that is able to show a\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>P<\/jats:sub>\n                    of 1.92\u2005s and a\n                    <jats:italic>\u03a6<\/jats:italic>\n                    <jats:sub>P<\/jats:sub>\n                    of 30\u2009% even in a less rigid matrix of poly(methyl methacrylate) (PMMA). Excitingly, OF\u2010BCz exhibited its potential as both a photocuring initiator and an in situ quality indicator, allowing for the visual detection of defects in photolithographic patterning.\n                  <\/jats:p>","DOI":"10.1002\/anie.202312534","type":"journal-article","created":{"date-parts":[[2023,11,16]],"date-time":"2023-11-16T01:19:25Z","timestamp":1700097565000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Ambient Phosphor with High Efficiency and Long Lifetime in Poly(Methyl Methacrylate) Through Charge\u2010Transfer\u2010Mediated Triplet Exciton Formation for Photolithography Applications"],"prefix":"10.1002","volume":"63","author":[{"given":"Ruyi","family":"Liu","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanhao","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caixia","family":"Fu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenzhen","family":"Zhu","sequence":"additional","affiliation":[{"name":"Werlchem New Materials Co., Ltd.  Chongqing 401121 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuan","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuan","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingjie","family":"Wang","sequence":"additional","affiliation":[{"name":"Werlchem New Materials Co., Ltd.  Chongqing 401121 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1733-4061","authenticated-orcid":false,"given":"Zhiyun","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education) College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,28]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202201761"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27914-0"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201820"},{"key":"e_1_2_3_5_1","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-019-0408-4"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005105"},{"key":"e_1_2_3_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202000880"},{"key":"e_1_2_3_9_1","unstructured":"\u00a0"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100872a054"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002555"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202003693"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202203254"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32029-1"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139385"},{"key":"e_1_2_3_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202208895"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC02557D"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2022.07.010"},{"key":"e_1_2_3_19_1","unstructured":"\u00a0"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1674940"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60310a002"},{"key":"e_1_2_3_22_1","unstructured":"\u00a0"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1968.0149"},{"key":"e_1_2_3_24_2","first-page":"241","volume-title":"Modern Molecular Photochemistry of Organic Molecules","author":"Turro N. J.","year":"2010"},{"key":"e_1_2_3_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0223-z"},{"key":"e_1_2_3_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001348"},{"key":"e_1_2_3_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601252"},{"key":"e_1_2_3_28_1","unstructured":"\u00a0"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003560"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC02263J"},{"key":"e_1_2_3_31_1","unstructured":"\u00a0"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.190823"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b18318"},{"key":"e_1_2_3_34_1","unstructured":"\u00a0"},{"key":"e_1_2_3_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7TC01958K"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01132-x"},{"key":"e_1_2_3_37_1","unstructured":"\u00a0"},{"key":"e_1_2_3_38_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(88)80325-7"},{"key":"e_1_2_3_39_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1999.tb08240.x"},{"key":"e_1_2_3_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60240a004"},{"key":"e_1_2_3_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201902087"},{"key":"e_1_2_3_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200059"},{"key":"e_1_2_3_43_1","unstructured":"Deposition number2249360 (for OF-BCz)contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_3_44_1","unstructured":"\u00a0"},{"key":"e_1_2_3_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11022"},{"key":"e_1_2_3_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12074"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202312534","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,6,20]],"date-time":"2024-06-20T10:02:13Z","timestamp":1718877733000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202312534"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,28]]},"references-count":46,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2024,1,22]]}},"alternative-id":["10.1002\/anie.202312534"],"URL":"https:\/\/doi.org\/10.1002\/anie.202312534","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,28]]},"assertion":[{"value":"2023-08-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-11-28","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202312534"}}