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Regulating product distribution remains challenging, such as achieving higher olefin selectivity, propylene\/ethylene (<jats:italic>P\/E<\/jats:italic>) and olefin\/paraffin (<jats:italic>O\/P<\/jats:italic>) ratios. A new pentasil zeolite Al\u2010IDM\u20101 with recently approved \u2212<jats:bold>ION<\/jats:bold> structure, composed of 17\u2010membered\u2010ring (MR) extra\u2010large lobed pores and intersected 10\u2010MR medium pores, shows a C<jats:sub>2\u20136<\/jats:sub><jats:sup>=<\/jats:sup> selectivity up to 85\u2009% and a high <jats:italic>O\/P<\/jats:italic> value of 14 in the conversion of syngas when being combined with Zn<jats:sub>a<\/jats:sub>Al<jats:sub>b<\/jats:sub>O<jats:sub>x<\/jats:sub> oxide. Moreover, for the high\u2010silica Al\u2010IDM\u20101 with Si\/Al ratio of 400, the selectivity of propylene and butene accounts for 88\u2009% in C<jats:sub>2\u20134<\/jats:sub><jats:sup>=<\/jats:sup>, resulting in high <jats:italic>P\/E<\/jats:italic> (&gt;4) and butene\/ethylene (<jats:italic>B\/E<\/jats:italic> &gt;3) ratios. The high C<jats:sub>3\u20134<\/jats:sub><jats:sup>=<\/jats:sup> selectivity is contributed by two main reasons, that is, the relatively weak acidity of Al\u2010IDM\u20101 zeolite enhances the olefin\u2010based cycle revealed by the probe reactions of methanol\u2010to\u2010propylene (MTP) and 1\u2010hexene cracking, and the rich isolated internal SiOH groups in Al\u2010IDM\u20101 promote the desorption of C<jats:sub>3\u20134<\/jats:sub><jats:sup>=<\/jats:sup>, once they are formed inside zeolite pores.<\/jats:p>","DOI":"10.1002\/anie.202313785","type":"journal-article","created":{"date-parts":[[2023,11,14]],"date-time":"2023-11-14T07:54:48Z","timestamp":1699948488000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Promoting Syngas to Olefins with Isolated Internal Silanols\u2010Enriched Al\u2010IDM\u20101 Aluminosilicate 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