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Specifically, the obtained octadecahedron BiVO\n                    <jats:sub>4<\/jats:sub>\n                    (Octa\u2010BiVO\n                    <jats:sub>4<\/jats:sub>\n                    ) performs a high response value (67) and short response time (47.4\u2005s) to 100\u2005ppm H\n                    <jats:sub>2<\/jats:sub>\n                    S with good stability for nearly 100\u2005days, as well as undisturbedness by moist air. With the combination of experimental and theoretical calculation results, the adsorption and carrier transfer behaviors of H\n                    <jats:sub>2<\/jats:sub>\n                    S molecules on the Octa\u2010BiVO\n                    <jats:sub>4<\/jats:sub>\n                    crystal surface are investigated. By adjusting the ratio of different crystal facets and controlling the facets with characteristic adsorption, we achieve improved anisotropic photoinduced carrier separation and high selectivity for a specific gas. Furthermore, this facial facet engineering can be extended to the synthesis of other sensing materials, offering huge opportunities for fundamental research and technological applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.202314891","type":"journal-article","created":{"date-parts":[[2023,11,7]],"date-time":"2023-11-07T03:24:40Z","timestamp":1699327480000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":52,"title":["Crystal Engineering of BiVO\n                    <sub>4<\/sub>\n                    for Photochemical Sensing of H\n                    <sub>2<\/sub>\n                    S Gas at Ultra\u2010low Concentration"],"prefix":"10.1002","volume":"62","author":[{"given":"Fei","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou Fujian 350116 P. R. 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