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In this work, an efficient electrochemical\u2010assisted MSR reaction for pure H<jats:sub>2<\/jats:sub> production at lower temperature (~140\u2009\u00b0C) is developed by coupling the electrocatalysis reaction into the MSR in a polymer electrolyte membrane electrolysis reactor. By electrochemically assisted, the two critical steps including the methanol dehydrogenation and water\u2010gas shift reaction are accelerated, which is attributed to decreasing the methanol dehydrogenation energy and promoting the dissociation of H<jats:sub>2<\/jats:sub>O to OH* by the applied potential. Furthermore, the reduced H<jats:sub>2<\/jats:sub> partial pressure by the hydrogen oxidation and reduction process further promotes MSR. The combination of these advantages not only efficiently decreases the MSR temperature but also achieves the high rate of hydrogen production of 505\u2005mmol\u2009H<jats:sub>2<\/jats:sub>\u2009g\u2009<jats:sub>Pt<\/jats:sub><jats:sup>\u22121<\/jats:sup> h<jats:sup>\u22121<\/jats:sup> with exceptionally high H<jats:sub>2<\/jats:sub> selectivity (99\u2009%) at 180\u2009\u00b0C and a low voltage (0.4\u2005V), and the productivity is about 30\u2010fold than that of traditional MSR. This study opens up a new avenue to design novel electrolysis cells for hydrogen production.<\/jats:p>","DOI":"10.1002\/anie.202315157","type":"journal-article","created":{"date-parts":[[2023,12,25]],"date-time":"2023-12-25T03:53:04Z","timestamp":1703476384000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Efficient Low\u2010temperature Hydrogen Production by Electrochemical\u2010assisted Methanol Steam Reforming"],"prefix":"10.1002","volume":"63","author":[{"given":"Qie","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemo\/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering Hunan University  Changsha, Hunan 410082 P. R. 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