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The mild conditions are compatible with a wide array of nonactivated trifluoromethyl aromatics bearing electron\u2010donating or electron\u2010neutral substituents, trifluoroacetamides, and various nonactivated terminal and internal alkenes, enabling straightforward access to synthetically valuable\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010\n                    <jats:italic>gem<\/jats:italic>\n                    \u2010difluoroalkyl boronates with high efficiency. Furthermore, this protocol is applicable to alkene\u2010tethered trifluoromethyl aromatics to furnish\n                    <jats:italic>gem<\/jats:italic>\n                    \u2010difluoromethylene\u2010containing cyclic compounds. Synthetic applications and preliminary mechanistic studies are also presented.\n                  <\/jats:p>","DOI":"10.1002\/anie.202315974","type":"journal-article","created":{"date-parts":[[2023,12,8]],"date-time":"2023-12-08T22:39:06Z","timestamp":1702075146000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Defluorinative Alkylboration of Alkenes Enabled by Dual Photoredox and Copper Catalysis"],"prefix":"10.1002","volume":"63","author":[{"given":"Yanmin","family":"Fan","sequence":"first","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical Engineering Center for Advanced Low-Dimension Materials Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhonghou","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical Engineering Center for Advanced Low-Dimension Materials Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical Engineering Center for Advanced Low-Dimension Materials Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengqing","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical Engineering Center for Advanced Low-Dimension Materials Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7969-0531","authenticated-orcid":false,"given":"Lingling","family":"Chu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical Engineering Center for Advanced Low-Dimension Materials Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,21]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","unstructured":"L.\u2005S. 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