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Typically, metal catalysts bearing chiral ligands as well as chiral organocatalysts have been employed for the enantioselective synthesis of organic compounds. In this review, we highlight the recent advances in main group catalysis for enantioselective reactions using the p\u2010block elements (boron, aluminium, phosphorus, bismuth) as a complementary and sustainable approach to generate chiral molecules. Several of these catalysts benefit in terms of high abundance, low toxicity, high selectivity, and excellent reactivity. This minireview summarises the utilisation of chiral p\u2010block element catalysts for asymmetric reactions to generate value\u2010added compounds.<\/jats:p>","DOI":"10.1002\/anie.202316461","type":"journal-article","created":{"date-parts":[[2023,12,1]],"date-time":"2023-12-01T08:18:04Z","timestamp":1701418684000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Recent Advances in Asymmetric Catalysis Using p\u2010Block Elements"],"prefix":"10.1002","volume":"63","author":[{"given":"Milan","family":"Pramanik","sequence":"first","affiliation":[{"name":"Cardiff Catalysis Institute School of Chemistry Cardiff University Translational Research Hub  Maindy Road Cathays, Cardiff CF24 4HQ Cymru\/Wales UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael G.","family":"Guerzoni","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute School of Chemistry Cardiff University Translational Research Hub  Maindy Road Cathays, Cardiff CF24 4HQ Cymru\/Wales UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emma","family":"Richards","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute School of Chemistry Cardiff University Translational Research Hub  Maindy Road Cathays, Cardiff CF24 4HQ Cymru\/Wales UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3142-2831","authenticated-orcid":false,"given":"Rebecca L.","family":"Melen","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute School of Chemistry Cardiff University Translational Research Hub  Maindy Road Cathays, Cardiff CF24 4HQ Cymru\/Wales UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,18]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020617)41:12<2008::AID-ANIE2008>3.0.CO;2-4"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1083622"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02957"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202200950"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00196A"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11408"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202201236"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.07.011"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar100101b"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28020642"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.6023\/cjoc202208018"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal12010005"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8OB02446D"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB01556E"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305449"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c02463"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201900104"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104788"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202200100"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.09.007"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000011"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.5059\/yukigoseikyokaishi.79.1065"},{"key":"e_1_2_7_23_1","doi-asserted-by":"crossref","unstructured":"X. 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