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Reports on their superior homologs are rare, and this has greatly limited the systematic study of their properties. In this work, a series of osma\u2010dehydro[11]annulenes with good air and thermal stability were prepared in high yields through a simple [10+1] strategy, by incorporating a metal fragment into conjugated ten\u2010carbon chains in a one\u2010pot reaction. They are the first monometallic aromatic metalla\u2010[<jats:italic>n<\/jats:italic>]annulenes with the ring size larger than 6, and their Craig\u2010H\u00fcckel hybrid aromaticity is supported by various physical and computational parameters. Besides, these complexes show versatile reactivities, not only giving further evidence for their aromaticity, but also demonstrating their physical and chemical properties can easily be regulated. This work enriches the metalla\u2010aromatic chemistry, and provides a new avenue for the synthesis of large metalla\u2010annulenes with different ring sizes.<\/jats:p>","DOI":"10.1002\/anie.202316885","type":"journal-article","created":{"date-parts":[[2023,12,23]],"date-time":"2023-12-23T03:30:20Z","timestamp":1703302220000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Craig\u2010H\u00fcckel Hybrid Aromatic Metalla\u2010dehydro[11]annulenes Constructed by a Formal [10+1] Cycloaddition Reaction"],"prefix":"10.1002","volume":"63","author":[{"given":"Kaidong","family":"Ruan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"},{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengyu","family":"Lu","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren","family":"Rao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"},{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiao\u2010Jiao","family":"Liu","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dafa","family":"Chen","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2688-6634","authenticated-orcid":false,"given":"Haiping","family":"Xia","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"},{"name":"Shenzhen Grubbs Institute Department of Chemistry Southern University of Science and Technology  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,11]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00257"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00135-z"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00713-2"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209138"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006198"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.172"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar600067n"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050541c"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200500705"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar010090s"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.3390\/sym2041846"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25030711"},{"key":"e_1_2_7_15_2","doi-asserted-by":"crossref","unstructured":"I. 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