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Here, Cu@ZnO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> encapsulation structure has been in situ constructed through gas\u2010phase migration of Zn species from ZnO particles onto surface of Cu nanoparticles under CO<jats:sub>2<\/jats:sub> hydrogenation atmosphere at 450\u2009\u00b0C. The gas\u2010phase deposition of Zn species onto the Cu surface and growth of ZnO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> overlayer is self\u2010limited under the high temperature and redox gas (CO<jats:sub>2<\/jats:sub>\/H<jats:sub>2<\/jats:sub>) conditions. Accordingly, high density ZnO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>\u2010Cu interface sites can be effectively tailored to have an enhanced activity in CO<jats:sub>2<\/jats:sub> hydrogenation to methanol. This work reveals a new route for the construction of active oxide\u2010metal interface and classic strong metal\u2010support interaction state through gas\u2010phase migration of support species induced by high temperature redox reaction atmosphere.<\/jats:p>","DOI":"10.1002\/anie.202316888","type":"journal-article","created":{"date-parts":[[2023,12,11]],"date-time":"2023-12-11T18:36:20Z","timestamp":1702319780000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Enhanced Methanol Synthesis over Self\u2010Limited ZnO<sub><i>x<\/i><\/sub> Overlayers on Cu Nanoparticles Formed via Gas\u2010Phase Migration Route"],"prefix":"10.1002","volume":"63","author":[{"given":"Tongyuan","family":"Song","sequence":"first","affiliation":[{"name":"State Key Laboratory of Catalysis Dalian Institute of Chemical Physics iChEM Chinese Academy of Sciences  Dalian 116023 China"},{"name":"University of Chinese Academy of Sciences  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