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However, only scarce examples can be found when it comes C\u2010to\u2010N\u2010transmutation reactions of aromatics that could lead to the facile synthesis of pyridines or other azaarenes. In this context, Levin and co\u2010workers recently disclosed a process leading to pyridines from the corresponding aryl azides via the regioselective nitrene internalization process. Notably, the transformation did not lead to any further modification of the rest of the aromatic skeleton. This innovative work enabled selectively accessing various pyridine derivatives through direct nitrogen scan operations on benzene derivatives, which were otherwise not feasible.<\/jats:p>","DOI":"10.1002\/anie.202317228","type":"journal-article","created":{"date-parts":[[2023,12,20]],"date-time":"2023-12-20T12:30:27Z","timestamp":1703075427000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Accessing Pyridines via a Nitrene Internalization Process"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3626-1520","authenticated-orcid":false,"given":"Namrata","family":"Kotwal","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Jammu  Jagti, NH-44 Nagrota Bypass Jammu 181221, J&amp;K India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8779-0652","authenticated-orcid":false,"given":"Pankaj","family":"Chauhan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Jammu  Jagti, NH-44 Nagrota Bypass Jammu 181221, J&amp;K India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,8]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm501100b"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.2174\/1389557521666210126143558"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202300074"},{"key":"e_1_2_3_5_1","unstructured":"\u00a0"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm5018169"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.6b01807"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0021-z"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.9b01180"},{"key":"e_1_2_3_10_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0043\u20131763623"},{"key":"e_1_2_3_11_1","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201945"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27687-6"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(66)80104-7"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00757a032"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c08464"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adj5331"},{"key":"e_1_2_3_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)76215-0"},{"key":"e_1_2_3_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06613-4"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202317228","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,3,10]],"date-time":"2025-03-10T03:16:03Z","timestamp":1741576563000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202317228"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1,8]]},"references-count":19,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2024,2,12]]}},"alternative-id":["10.1002\/anie.202317228"],"URL":"https:\/\/doi.org\/10.1002\/anie.202317228","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,1,8]]},"assertion":[{"value":"2023-11-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-01-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202317228"}}