{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T17:20:13Z","timestamp":1791912013293,"version":"4.3.4"},"reference-count":27,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2024,2,2]],"date-time":"2024-02-02T00:00:00Z","timestamp":1706832000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U20A20249"],"award-info":[{"award-number":["U20A20249"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21972108"],"award-info":[{"award-number":["21972108"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20438"],"award-info":[{"award-number":["U22A20438"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFB3800300"],"award-info":[{"award-number":["2021YFB3800300"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010877","name":"Science, Technology and Innovation Commission of Shenzhen Municipality","doi-asserted-by":"publisher","award":["KCXST20221021111216037"],"award-info":[{"award-number":["KCXST20221021111216037"]}],"id":[{"id":"10.13039\/501100010877","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,3,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Chemical presodiation (CP) is an effective strategy to enhance energy density of sodium ion batteries. However, the sodiation reagents reported so far are basically polycyclic aromatic hydrocarbons (PAHs) wth low reductive potential (~0.1\u2005V\n                    <jats:italic>vs<\/jats:italic>\n                    . Na\n                    <jats:sup>+<\/jats:sup>\n                    \/Na), which could easily cause over\u2010sodiation and structural deterioration of the presodiated cathodes. In this work, Aromatic ketones (AKs) are rationally designed as mild presodiating reagents by introducing a carbonyl group (C=O) into PAHs to balance the conjugated and inductive effect. As the representatives, two compounds 9\u2010Fluorenoneb (9\u2010FN) and Benzophenone (BP) manifest favorable equilibrium potential of 1.55\u2005V and 1.07\u2005V (\n                    <jats:italic>vs<\/jats:italic>\n                    . Na\n                    <jats:sup>+<\/jats:sup>\n                    \/Na), respectively. Note that 9\u2010FN demonstrates versatile presodiating capability toward multiple Na uptake hosts (tunneled Na\n                    <jats:sub>0.44<\/jats:sub>\n                    MnO\n                    <jats:sub>2<\/jats:sub>\n                    , layered Na\n                    <jats:sub>0.67<\/jats:sub>\n                    Ni\n                    <jats:sub>0.33<\/jats:sub>\n                    Mn\n                    <jats:sub>0.67<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , polyanionic Na\n                    <jats:sub>4<\/jats:sub>\n                    Fe\n                    <jats:sub>2.91<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    , Na\n                    <jats:sub>3<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    and Na\n                    <jats:sub>3<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>3<\/jats:sub>\n                    ), enabling greatly improved initial charging capacity of the cathode to balance the irrevisible capacity of the anode. Our results indicate that the Aromatic ketones are competitive presodiating cathodic reagents for high\u2010performance sodium\u2010ion batteries, and will inspire more studies and application attempts in the future.\n                  <\/jats:p>","DOI":"10.1002\/anie.202317439","type":"journal-article","created":{"date-parts":[[2024,1,22]],"date-time":"2024-01-22T07:53:25Z","timestamp":1705910005000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Aromatic Ketones as Mild Presodiating Reagents toward Cathodes for High\u2010Performance Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"63","author":[{"given":"Shihao","family":"Zhang","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kean","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangjun","family":"Pu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiying","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanan","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Along","family":"Zhao","sequence":"additional","affiliation":[{"name":"Shenzhen Janaenergy techonulogy Co., Ltd.  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyang","family":"Chen","sequence":"additional","affiliation":[{"name":"Shenzhen Janaenergy techonulogy Co., Ltd.  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongjin","family":"Fang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1526-7336","authenticated-orcid":false,"given":"Zhongxue","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Hydraulic Machinery Transients, Ministry of Education, School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6092-5652","authenticated-orcid":false,"given":"Yuliang","family":"Cao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,2,2]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104167"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201805427"},{"key":"e_1_2_3_3_1","volume":"23","author":"Ye M.","year":"2022","journal-title":"Mater. 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