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Compared to inorganic materials, coordination nanosheets have virtually infinite combinations, leading to tunability of physical properties and are promising candidates for heterostructure fabrication. Although stacking of coordination materials into vertical heterostructures is widely reported, reports of lateral coordination material heterostructures are few. Here we show the successful fabrication of a seamless lateral heterojunction showing diode behaviour, by sequential and spatially limited immersion of a new metalladithiolene coordination nanosheet, Zn<jats:sub>3<\/jats:sub>BHT, into aqueous Cu(II) and Fe(II) solutions. Upon immersion, the Zn centres in insulating Zn<jats:sub>3<\/jats:sub>BHT are replaced by Cu or Fe ions, resulting in conductivity. The transmetallation is spatially confined, occurring only within the immersed area. We anticipate that our results will be a starting point towards exploring transmetallation of various two\u2010dimensional materials to produce lateral heterojunctions, by providing a new and facile synthetic route.<\/jats:p>","DOI":"10.1002\/anie.202318181","type":"journal-article","created":{"date-parts":[[2024,1,5]],"date-time":"2024-01-05T05:19:22Z","timestamp":1704431962000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Lateral Heterometal Junction Rectifier Fabricated by Sequential Transmetallation of Coordination Nanosheet**"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9806-260X","authenticated-orcid":false,"given":"Choon Meng","family":"Tan","sequence":"first","affiliation":[{"name":"Research Institute for Science and Technology Tokyo University of Science  2641 Yamazaki Noda Chiba 278 8510 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