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Here we determine experimentally a universal parameter for their strength that is simply based on the size of the interacting contact surfaces. Toward this goal we designed a new cyclophane based on terrylene bisimide (TBI) \u03c0\u2010walls connected by <jats:italic>para<\/jats:italic>\u2010xylylene spacer units. With its extended \u03c0\u2010surface this cyclophane proved to be an excellent and universal host for the complexation of \u03c0\u2010conjugated guests, including small and large polycyclic aromatic hydrocarbons (PAHs) as well as dye molecules. The observed binding constants range up to 10<jats:sup>8<\/jats:sup>\u2005M<jats:sup>\u22121<\/jats:sup> and show a linear dependence on the 2D area size of the guest molecules. This correlation can be used for the prediction of binding constants and for the design of new host\u2013guest systems based on the herewith derived universal Gibbs interaction energy parameter of 0.31\u2005kJ\/mol\u00c5<jats:sup>2<\/jats:sup> in chloroform.<\/jats:p>","DOI":"10.1002\/anie.202318451","type":"journal-article","created":{"date-parts":[[2024,2,28]],"date-time":"2024-02-28T15:15:16Z","timestamp":1709133316000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["A Terrylene Bisimide based Universal Host for Aromatic Guests to Derive Contact Surface\u2010Dependent Dispersion Energies"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6595-1112","authenticated-orcid":false,"given":"Jessica","family":"R\u00fche","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Organische Chemie Universit\u00e4t W\u00fcrzburg  Am Hubland 97074 W\u00fcrzburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8837-2690","authenticated-orcid":false,"given":"Megha","family":"Rajeevan","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram (IISER TVM)  Vithura, Thiruvananthapuram 695551 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0937-4431","authenticated-orcid":false,"given":"Kazutaka","family":"Shoyama","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Organische Chemie Universit\u00e4t W\u00fcrzburg  Am Hubland 97074 W\u00fcrzburg Germany"},{"name":"Center for Nanosystems Chemistry (CNC) Universit\u00e4t W\u00fcrzburg  Theodor-Boveri-Weg 97074 W\u00fcrzburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1625-1771","authenticated-orcid":false,"given":"Rotti Srinivasamurthy","family":"Swathi","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram (IISER TVM)  Vithura, Thiruvananthapuram 695551 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7245-0471","authenticated-orcid":false,"given":"Frank","family":"W\u00fcrthner","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Organische Chemie Universit\u00e4t W\u00fcrzburg  Am Hubland 97074 W\u00fcrzburg Germany"},{"name":"Center for Nanosystems Chemistry (CNC) Universit\u00e4t W\u00fcrzburg  Theodor-Boveri-Weg 97074 W\u00fcrzburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,18]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","first-page":"468","volume-title":"Supramolecular Chemistry","author":"Kubik S.","year":"2021"},{"key":"e_1_2_3_3_2","first-page":"381","volume-title":"Supramolecular Chemistry","author":"Steed J. 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