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Thus, while the PA is found molecularly dissolved in chloroform, the addition of Ag<jats:sup>+<\/jats:sup> ions induce its aggregation through the formation of an axially chiral metallo\u2010supramolecular aggregate with high thermal stable properties. In this case, the ability of the metal ion to coordinate the PA triple bond, combined with the argentophilicity of the metal ion and the planarity of the phenylacetylene drives to the formation of a helical coordination polymer, whose <jats:italic>P<\/jats:italic> or <jats:italic>M<\/jats:italic> axial chirality is determined by the chirality of the sulfoxide used as substituent of the PA. 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