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Here, we report the sustainable production of amino acids from biomass\u2010derived hydroxy acids with high activity under visible\u2010light irradiation and mild conditions, using atomic ruthenium\u2010promoted cadmium sulfide (Ru\n                    <jats:sub>1<\/jats:sub>\n                    \/CdS). On a metal basis, the optimized Ru\n                    <jats:sub>1<\/jats:sub>\n                    \/CdS exhibits a maximal alanine formation rate of 26.0\u2005mol\n                    <jats:sub>Ala<\/jats:sub>\n                    \u2009\u22c5\u2009g\n                    <jats:sub>Ru<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009\u22c5\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is 1.7\u2005times and more than two orders of magnitude higher than that of its nanoparticle counterpart and the conventional thermocatalytic process, respectively. Integrated spectroscopic analysis and density functional theory calculations attribute the high performance of Ru\n                    <jats:sub>1<\/jats:sub>\n                    \/CdS to the facilitated charge separation and O\u2212H bond dissociation of the\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010hydroxy group, here of lactic acid. The operando nuclear magnetic resonance further infers a unique \u201cdouble activation\u201d mechanism of both the CH\u2212OH and CH\n                    <jats:sub>3<\/jats:sub>\n                    \u2212CH\u2212OH structures in lactic acid, which significantly accelerates its photocatalytic amination toward alanine.\n                  <\/jats:p>","DOI":"10.1002\/anie.202320014","type":"journal-article","created":{"date-parts":[[2024,4,10]],"date-time":"2024-04-10T11:00:00Z","timestamp":1712746800000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":58,"title":["Atomic Ruthenium\u2010Promoted Cadmium Sulfide for Photocatalytic Production of Amino Acids from Biomass Derivatives"],"prefix":"10.1002","volume":"63","author":[{"given":"Wulin","family":"Li","sequence":"first","affiliation":[{"name":"Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and Materials Nanjing Forestry University  Longpan Road 159 Nanjing 210037 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiuhui","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Changjiang West Road 66 Qingdao 266580 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bei\u2010Bei","family":"Xu","sequence":"additional","affiliation":[{"name":"Physics Department Shanghai Key Laboratory of Magnetic Resonance East China Normal University  Shanghai 200062 China"},{"name":"School of New Energy Nanjing University of Science and Technology  Wu Xi Shi, Jiangyin 214400 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology Shanghai Tech University  Huaxia Middle Road 393 Shanghai 201210 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