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The electrocatalytic reactions involving nitrogen oxides (NO<jats:sub>x<\/jats:sub>) offered a potential strategy for synthesizing various nitrogenous chemicals. However, it is currently hindered by low selectivity\/efficiency and limited reaction pathways, mainly due to the difficulties in controllable generation and utilization of nitrogenous intermediates. In this minireview, focusing on nitrogenous intermediates in NO<jats:sub>x<\/jats:sub>\u2010involved electrocatalytic reactions, we discuss newly developed methodologies for studying and controlling the generation, conversion, and utilizing of nitrogenous intermediates, which enable recent developments in NO<jats:sub>x<\/jats:sub>\u2010involved electrocatalytic reactions that yield various products, including ammonia (NH<jats:sub>3<\/jats:sub>), organonitrogen molecules, and nitrogenous compounds exhibiting unconventional oxidation states. 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