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However, the single metallic site limits the comprehensive reaction performance in most reactions. Here, we demonstrated a photo\u2010induced neighbour\u2010deposition strategy for the precise synthesis of diatomic Ir\n                    <jats:sub>1<\/jats:sub>\n                    Pd\n                    <jats:sub>1<\/jats:sub>\n                    on In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    applied for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol. The proximity synergism between diatomic sites enabled a striking promotion in both CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion (10.5\u2009%) and methanol selectivity (97\u2009%) with good stability of 100\u2005h run. It resulted in record\u2010breaking space\u2010time yield to methanol (187.1\u2005g\n                    <jats:sub>MeOH<\/jats:sub>\n                    \u2009g\n                    <jats:sub>metal<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2005hour\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). The promotional effect mainly originated from stronger CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption on Ir site with assistance of H\u2010spillover from Pd site, thus leading to a lower energy barrier for *HCOO pathway. It was confirmed that this synergistic effect strongly depended on the dual\u2010site distance in an angstrom scale, which was attributed to weaker *H spillover and less electron transfer from Pd to Ir site as the Pd\u2010to\u2010Ir distance increased. The average dual\u2010site distance was evaluated by our firstly proposed photoelectric model. Thus, this study introduced a pioneering strategy to precisely synthesize homonuclear\/heteronuclear diatomic catalysts for facilitating the desired reaction route via diatomic synergistic catalysis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202401168","type":"journal-article","created":{"date-parts":[[2024,2,9]],"date-time":"2024-02-09T22:12:15Z","timestamp":1707516735000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Photoinduced Precise Synthesis of Diatomic Ir\n                    <sub>1<\/sub>\n                    Pd\n                    <sub>1<\/sub>\n                    \u2010In\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    for CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol via Angstrom\u2010Scale\u2010Distance Dependent Synergistic Catalysis"],"prefix":"10.1002","volume":"63","author":[{"given":"Jie","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongjian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ke","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering School of Chemical and Material Engineering Jiangnan University  Wuxi 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