{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,13]],"date-time":"2026-11-13T17:00:16Z","timestamp":1794589216101,"version":"4.9.1"},"reference-count":30,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2024,5,27]],"date-time":"2024-05-27T00:00:00Z","timestamp":1716768000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379127"],"award-info":[{"award-number":["22379127"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2023M743354"],"award-info":[{"award-number":["2023M743354"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Inorganic solid\u2010state electrolytes (SSEs) play a vital role in high\u2010energy all\u2010solid\u2010state batteries (ASSBs). However, the current method of SSE preparation usually involves high\u2010energy mechanical ball milling and\/or a high\u2010temperature annealing process, which is not suitable for practical application. Here, a facile strategy is developed to realize the scalable synthesis of cost\u2010effective aluminum\u2010based oxyhalide SSEs, which involves a self\u2010propagating method by the exothermic reaction of the raw materials. This strategy enables the synthesis of various aluminum\u2010based oxyhalide SSEs with tunable components and high ionic conductivities (over 10\n                    <jats:sup>\u22123<\/jats:sup>\n                    \u2005S\u2009cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 25\u2009\u00b0C) for different cations (Li\n                    <jats:sup>+<\/jats:sup>\n                    , Na\n                    <jats:sup>+<\/jats:sup>\n                    , Ag\n                    <jats:sup>+<\/jats:sup>\n                    ). It is elucidated that the amorphous matrix, which mainly consists of various oxidized chloroaluminate species that provide numerous sites for smooth ion migration, is actually the key factor for the achieved high conductivities. Benefit from their easy synthesis, low cost, and low weight, the aluminum\u2010based oxyhalide SSEs synthesized by our approach could further promote practical application of high\u2010energy\u2010density ASSBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202401373","type":"journal-article","created":{"date-parts":[[2024,4,25]],"date-time":"2024-04-25T00:58:25Z","timestamp":1714006705000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":62,"title":["A Universal Self\u2010Propagating Synthesis of Aluminum\u2010Based Oxyhalide Solid\u2010State Electrolytes"],"prefix":"10.1002","volume":"63","author":[{"given":"Simeng","family":"Zhang","sequence":"first","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Xu","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"},{"name":"School of Materials Science and Engineering Hubei University  Wuhan 430062 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han","family":"Wu","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianlu","family":"Pang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Materials for Integrated Circuits Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai 200050. P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201204 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changtai","family":"Zhao","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyi","family":"Yue","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiamin","family":"Fu","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Materials Engineering University of Western Ontario  London ON N6A 5B9 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengjie","family":"Xia","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangzhen","family":"Zhu","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanzhi","family":"Wang","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"},{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Duan","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Materials Engineering University of Western Ontario  London ON N6A 5B9 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biwei","family":"Xiao","sequence":"additional","affiliation":[{"name":"Solid State Batteries Research Center GRINM (Guangdong) Institute for Advanced Materials and Technology  Foshan Guangdong 528051 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Mei","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Hubei University  Wuhan 430062 P. R. 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