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As a novel 2D material, polymeric fullerenes (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> with distinctive properties are very promising for the development of innovative membranes. In this work, we report the construction of a 2D (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> nanosheet membrane for organic solvent separation. The pathways of the (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> nanosheet membrane are constructed by sub\u20101\u2010nm lateral channels and nanoscale in\u2010plane pores created by the depolymerization of the (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> nanosheets. Attributing to ordered and shortened transport pathways, the ultrathin porous (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> membrane is superior in organic solvent separation. The hexane, acetone, and methanol fluxes are up to 1146.3\u00b153, 900.4\u00b141, and 879.5\u00b142\u2005kg\u2009\u22c5\u2009m<jats:sup>\u22122<\/jats:sup>\u2009\u22c5\u2009h<jats:sup>\u22121<\/jats:sup>, respectively, which are up to 130 times higher than those of the state\u2010of\u2010the\u2010art membranes with similar dye rejection. Our findings demonstrate the prospect of 2D (C<jats:sub>60<\/jats:sub>)<jats:sub>\u221e<\/jats:sub> as a promising nanofiltration membrane in the separation of organic solvents from macromolecular compounds such as dyes, drugs, hormones, etc.<\/jats:p>","DOI":"10.1002\/anie.202401747","type":"journal-article","created":{"date-parts":[[2024,2,19]],"date-time":"2024-02-19T18:48:15Z","timestamp":1708368495000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Ultrathin Two\u2010Dimensional Porous Fullerene Membranes for Ultimate Organic Solvent Separation"],"prefix":"10.1002","volume":"63","author":[{"given":"Xiaofang","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifang","family":"Mu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunxin","family":"Jin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yayu","family":"Wei","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinlin","family":"Hao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huanting","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering Monash University  Clayton Victoria 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00fcrgen","family":"Caro","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry and Electrochemistry Leibniz University Hanover  Callinstrasse 3\u2005A 30167 Hannover Deutschland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9727-4379","authenticated-orcid":false,"given":"Aisheng","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular &amp; Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  500, Dongchuan Road Shanghai 200241 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,5]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409783"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01347A"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201806090"},{"key":"e_1_2_8_5_1","unstructured":"\u00a0"},{"key":"e_1_2_8_6_2","author":"Huang L.","year":"2023","journal-title":"Angew. 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