{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T00:43:33Z","timestamp":1792197813830,"version":"4.4.0"},"reference-count":34,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2024,5,28]],"date-time":"2024-05-28T00:00:00Z","timestamp":1716854400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22005250"],"award-info":[{"award-number":["22005250"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Glass metal\u2013organic framework (MOF) films can be fabricated from their crystalline counterparts through a melt\u2010quenching process and are prospective candidates for gas separation because of the elimination of the grain boundaries in crystalline MOF films. However, current techniques are limited to producing glass MOF films with a thickness of tens of micrometers, which leads to ultralow gas permeances. Here, we report a novel cathodic deposition\u2010assisted synthesis of glass ZIF\u201062 films with a thickness as low as ~1\u2005\u03bcm. Electrochemical analyses and deposition experiments suggest that the cathodic deposition can lead to pure crystalline ZIF\u201062 films with a controllable thickness of ~2\u2005\u03bcm to ~15\u2005\u03bcm. Accordingly, glass ZIF\u201062 films with a thickness of ~1\u2005\u03bcm to ~10\u2005\u03bcm can be obtained after a thermal treatment. The fabricated defect\u2010free glass ZIF\u201062 film measuring 2\u2005\u03bcm in thickness shows a remarkable CO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    selectivity of 31.4 and 33.4, respectively, with a CO\n                    <jats:sub>2<\/jats:sub>\n                    permeance which is over 30 times higher than the best\u2010performing glass ZIF\u201062 films in literature.\n                  <\/jats:p>","DOI":"10.1002\/anie.202401817","type":"journal-article","created":{"date-parts":[[2024,4,23]],"date-time":"2024-04-23T13:57:07Z","timestamp":1713880627000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Cathodic Deposition\u2010Assisted Synthesis of Thin Glass MOF Films for High\u2010Performance Gas Separations"],"prefix":"10.1002","volume":"63","author":[{"given":"Sijie","family":"Xie","sequence":"first","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyu","family":"Tan","sequence":"additional","affiliation":[{"name":"Centre for Surface Chemistry and Catalysis KU Leuven  Celestijnenlaan 200F 3001 Leuven Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhong","family":"Xue","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pieter","family":"Geysens","sequence":"additional","affiliation":[{"name":"Department of Chemistry KU Leuven  Celestijnenlaan 200F, P.O. box 2404 B-3001 Leuven Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Pan","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyu","family":"Zhou","sequence":"additional","affiliation":[{"name":"ZJU-Hangzhou Global Scientific and Technological Innovation Centre Zhejiang University  Hangzhou 311200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3667-4280","authenticated-orcid":false,"given":"Xuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"},{"name":"ZJU-Hangzhou Global Scientific and Technological Innovation Centre Zhejiang University  Hangzhou 311200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivo F. J.","family":"Vankelecom","sequence":"additional","affiliation":[{"name":"Centre for Surface Chemistry and Catalysis KU Leuven  Celestijnenlaan 200F 3001 Leuven Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan","family":"Fransaer","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,28]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2019.06.001"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-04763-5"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2023.135845"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.012"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108485"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2019.06.022"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat4123"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2011.12.074"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0206-2"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201806445"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13220"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.104.115503"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02088-w"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213388"},{"key":"e_1_2_7_17_2","author":"Castillo-Blas C.","year":"2024","journal-title":"Chem. Soc. Rev."},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201915807"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2022.120611"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC03179E"},{"key":"e_1_2_7_21_1","author":"Smirnova O.","year":"2023","journal-title":"Nat. Mater."},{"key":"e_1_2_7_22_1","first-page":"1","author":"Yang Z.","year":"2023","journal-title":"Nat. Mater."},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2009.11.022"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2041546"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808465"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aao6827"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnoncrysol.2019.119806"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz0251"},{"key":"e_1_2_7_30_1","unstructured":"\u00a0"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05558"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.1c00010"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2008.04.030"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2020.116993"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202401817","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,10,25]],"date-time":"2024-10-25T06:44:29Z","timestamp":1729838669000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202401817"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,28]]},"references-count":34,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2024,7]]}},"alternative-id":["10.1002\/anie.202401817"],"URL":"https:\/\/doi.org\/10.1002\/anie.202401817","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,5,28]]},"assertion":[{"value":"2024-01-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-05-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401817"}}