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Hemiprotonated sulfur dioxide [(SO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>H][Sb<jats:sub>2<\/jats:sub>F<jats:sub>11<\/jats:sub>] was obtained from the solvent SO<jats:sub>2<\/jats:sub> and the monoprotonated sulfur dioxide [OSOD][Sb<jats:sub>2<\/jats:sub>F<jats:sub>11<\/jats:sub>], using 1,1,1,2\u2010tetrafluoroethane as solvent. For both compounds, single crystals were obtained and an X\u2010ray structure analysis was conducted. Furthermore, the salts were characterized by Raman spectroscopy and the results were discussed together with quantum chemical calculations on the M06\u20102X\/aug\u2010cc\u2010pVTZ level of theory.<\/jats:p>","DOI":"10.1002\/anie.202401953","type":"journal-article","created":{"date-parts":[[2024,3,21]],"date-time":"2024-03-21T17:35:44Z","timestamp":1711042544000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis and Structure of Protonated Sulfur Dioxide"],"prefix":"10.1002","volume":"63","author":[{"given":"Christoph","family":"Jessen","sequence":"first","affiliation":[{"name":"Department of Chemistry Ludwig-Maximilian University of Munich  Butenandtstr. 5\u201313 81377 M\u00fcnchen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7307-4516","authenticated-orcid":false,"given":"Andreas J.","family":"Kornath","sequence":"additional","affiliation":[{"name":"Department of Chemistry Ludwig-Maximilian University of Munich  Butenandtstr. 5\u201313 81377 M\u00fcnchen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,4,9]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470421604"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/B415425H"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460005"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00076a055"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704645"},{"key":"e_1_2_3_6_1","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00470a023"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00281a009"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.3491510"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp22675d"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201000920"},{"key":"e_1_2_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000252"},{"key":"e_1_2_3_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja972602x"},{"key":"e_1_2_3_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200461847"},{"key":"e_1_2_3_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198803911"},{"key":"e_1_2_3_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200745"},{"key":"e_1_2_3_17_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X5200109X"},{"key":"e_1_2_3_18_1","unstructured":"\u00a0"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1293-2558(02)00036-5"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00049a030"},{"key":"e_1_2_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0206903"},{"key":"e_1_2_3_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100785a001"},{"key":"e_1_2_3_23_1","unstructured":"S.\u2005K. 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