{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T15:47:26Z","timestamp":1792511246396,"version":"4.5.0"},"reference-count":68,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2024,6,7]],"date-time":"2024-06-07T00:00:00Z","timestamp":1717718400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001839","name":"University Grants Committee","doi-asserted-by":"publisher","award":["T23-713\/22-R"],"award-info":[{"award-number":["T23-713\/22-R"]}],"id":[{"id":"10.13039\/501100001839","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001839","name":"University Grants Committee","doi-asserted-by":"publisher","award":["PF20-48638"],"award-info":[{"award-number":["PF20-48638"]}],"id":[{"id":"10.13039\/501100001839","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007402","name":"Environment and Conservation Fund","doi-asserted-by":"publisher","award":["ECF 2021-152"],"award-info":[{"award-number":["ECF 2021-152"]}],"id":[{"id":"10.13039\/501100007402","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,7,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Solar\u2010driven upgrading of biomass\u2010derived 5\u2010hydroxylmethylfurfural (HMF) to 2,5\u2010furandicarboxylic acid (FDCA) holds great promise for sustainable production of bio\u2010plastics and resins. However, the process is limited by poor selectivity and sluggish kinetics due to the vertical coordination of HMF at relatively strong metal sites. Here, we purposely developed a Cu(II) porphyrin framework featuring side\u2010chain incorporated urea linkages, denoted as TBUPP\u2212Cu MOF, to render HMF a weak hydrogen bond at the urea site and flat adsorption via \u03c0\u2013\u03c0 stacking with the benzene moiety. The unique configuration promotes the approaching of \u2212CHO of HMF to the photoexcited porphyrin ring towards kinetically and thermodynamically favourable intermediate formation and subsequent desorption. The charge localisation and orbital energy alignment enable the selective activation of O\n                    <jats:sub>2<\/jats:sub>\n                    over the porphyrin to generate \u22c5O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    instead of highly oxidative H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    and \u22c5OH via spin\u2010flip electron transfer, which drive the ambient oxidation of proximal \u2212CHO. The effective utilisation of redox species and circumvented over\u2010oxidation facilitate a FDCA selectivity of &gt;90\u2009% with a high turnover number of 193\u2005mol\n                    <jats:sub>HMF<\/jats:sub>\n                    \u2009mol\n                    <jats:sub>Cu<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The facile purification of high\u2010purity FDCA and zero\u2010waste recycling of intermediates and durable catalyst feature TBUPP\u2212Cu MOF a promising photo\u2010oxidation platform towards net\u2010zero biorefining and organic transformations.\n                  <\/jats:p>","DOI":"10.1002\/anie.202402694","type":"journal-article","created":{"date-parts":[[2024,4,28]],"date-time":"2024-04-28T22:08:35Z","timestamp":1714342115000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Hydrogen\u2010Bond\u2010Enhanced Photoreforming of Biomass Furans over a Urea\u2010Incorporated Cu(II) Porphyrin Framework"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0000-9155","authenticated-orcid":false,"given":"Yingchuan","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry The University of Hong Kong  Hong Kong SAR 999077 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanzhang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Hong Kong  Hong Kong SAR 999077 P. R. China"},{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan 430072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fupeng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Xiao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan 430072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangri","family":"Jia","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Hong Kong  Hong Kong SAR 999077 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenchao","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Hong Kong  Hong Kong SAR 999077 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fu\u2010Sheng","family":"Ke","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan 430072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5404-3215","authenticated-orcid":false,"given":"Zhengxiao","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of Hong Kong  Hong Kong SAR 999077 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,7]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00041H"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00407-8"},{"key":"e_1_2_6_3_1","unstructured":"\u00a0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00174"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309478"},{"key":"e_1_2_6_6_1","unstructured":"\u00a0"},{"key":"e_1_2_6_7_2","volume":"10","author":"Li Q.","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-022-00359-9"},{"key":"e_1_2_6_9_1","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122140"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08861"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02551"},{"key":"e_1_2_6_13_1","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c05357"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204225"},{"key":"e_1_2_6_16_1","unstructured":"\u00a0"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08657"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202304985"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.124699"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.add7417"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2022.01.003"},{"key":"e_1_2_6_22_1","unstructured":"\u00a0"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00373"},{"key":"e_1_2_6_24_2","volume":"34","author":"Wang H.","year":"2022","journal-title":"Adv. Mater."},{"key":"e_1_2_6_25_1","unstructured":"\u00a0"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114253"},{"key":"e_1_2_6_27_2","author":"Wu Y.","year":"2023","journal-title":"Adv. Mater."},{"key":"e_1_2_6_28_1","unstructured":"\u00a0"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03825"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2108118"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.7150\/thno.25433"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja307953m"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c09301"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200200561"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209289"},{"key":"e_1_2_6_36_1","unstructured":"\u00a0"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310934"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05032"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310476"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122670"},{"key":"e_1_2_6_41_1","unstructured":"\u00a0"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9530376"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07410"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08723"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.8b01502"},{"key":"e_1_2_6_46_1","unstructured":"\u00a0"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00161"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC04814D"},{"key":"e_1_2_6_49_1","unstructured":"\u00a0"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122560"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-800127-1.00002-3"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-25726-w"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201807647"},{"key":"e_1_2_6_54_1","unstructured":"\u00a0"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122140"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.01.001"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c01143"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.156036"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.3c04374"},{"key":"e_1_2_6_60_1","unstructured":"\u00a0"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.26812"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP00127A"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b10161"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0370488"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.2c00050"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12074"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2873"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202402694","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,21]],"date-time":"2025-05-21T01:53:06Z","timestamp":1747792386000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202402694"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,6,7]]},"references-count":68,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2024,7,8]]}},"alternative-id":["10.1002\/anie.202402694"],"URL":"https:\/\/doi.org\/10.1002\/anie.202402694","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,7]]},"assertion":[{"value":"2024-02-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-06-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202402694"}}