{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T13:08:35Z","timestamp":1789564115603,"version":"build-2803163510"},"reference-count":83,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2024,5,2]],"date-time":"2024-05-02T00:00:00Z","timestamp":1714608000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,6,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Herein, two atomically precise silver nanoclusters, <jats:bold>Ag54<\/jats:bold> and <jats:bold>Ag33<\/jats:bold>, directed by inner anion templates (CrO<jats:sub>4<\/jats:sub><jats:sup>2\u2212<\/jats:sup> and\/or Cl<jats:sup>\u2212<\/jats:sup>), are initially isolated as a mixed phase from identical reactants across a wide temperature range (20\u201380\u2009\u00b0C). Interestingly, fine\u2010tuning the reaction temperature can realize pure phase synthesis of the two nanoclusters; that is, a metastable <jats:bold>Ag54<\/jats:bold> is kinetically formed at a low temperature (20\u2009\u00b0C), whereas such a system is steered towards a thermodynamically stable <jats:bold>Ag33<\/jats:bold> at a relatively high temperature (80\u2009\u00b0C). Electrospray ionization mass spectrometry illustrates that the stability of <jats:bold>Ag33<\/jats:bold> is superior to that of <jats:bold>Ag54<\/jats:bold>, which is further supported by density functional theory calculations. Importantly, the difference in structural stability can influence the pathway of 1,4\u2010bis(pyrid\u20104\u2010yl)benzene induced transformation reaction starting from <jats:bold>Ag54<\/jats:bold> and <jats:bold>Ag33<\/jats:bold>. The former undergoes a dramatic breakage\u2010reorganization process to form an Ag<jats:sub>31<\/jats:sub> dimer (<jats:bold>Ag31<\/jats:bold>), while the same product can be also achieved from the latter following a noninvasive ligand exchange process. Both the <jats:bold>Ag54<\/jats:bold> and <jats:bold>Ag33<\/jats:bold> have the potential for further remote laser ignition applications. This work not only demonstrates how temperature controls the isolation of a specific phase, but also sheds light on the structural transformation pathway of nanoclusters with different stability.<\/jats:p>","DOI":"10.1002\/anie.202403464","type":"journal-article","created":{"date-parts":[[2024,4,6]],"date-time":"2024-04-06T06:04:40Z","timestamp":1712383480000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Temperature\u2010Controlled Selective Formation of Silver Nanoclusters and Their Transformation to the Same Product"],"prefix":"10.1002","volume":"63","author":[{"given":"Zhi","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University  250100 Ji'nan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuchen","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Kansas State University  66506 Manhattan Kansas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian\u2010Yang","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University  250100 Ji'nan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University  250100 Ji'nan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christine M.","family":"Aikens","sequence":"additional","affiliation":[{"name":"Department of Chemistry Kansas State University  66506 Manhattan Kansas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Yong","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Henan Normal University  453007 Xinxiang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohammad","family":"Azam","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Science King Saud University  PO BOX 2455 11451 Riyadh Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen\u2010Ho","family":"Tung","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University  250100 Ji'nan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5966-1207","authenticated-orcid":false,"given":"Di","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University  250100 Ji'nan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,2]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00703"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00769"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00329"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500506r"},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00376"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202005328"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00773"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012921"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901750"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02098"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04638"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.adh2365"},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00065"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c04832"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10569"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b07088"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05243"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06682"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008402"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CE00589J"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/a809346f"},{"key":"e_1_2_7_26_1","unstructured":"\u00a0"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b01122"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3422"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19789-4"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja306923a"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906425"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1600323"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.0c01204"},{"key":"e_1_2_7_34_1","unstructured":"\u00a0"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja042218h"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2028102"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp101764q"},{"key":"e_1_2_7_38_1","unstructured":"\u00a0"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460671"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108994"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg500978s"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic100181d"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201604540"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature20771"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9667"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11836"},{"key":"e_1_2_7_47_1","unstructured":"\u00a0"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1QI00684C"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR07124B"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00876A"},{"key":"e_1_2_7_51_1","unstructured":"\u00a0"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja900676f"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07779"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600229"},{"key":"e_1_2_7_55_1","unstructured":"Deposition Numbers 2301248 (forAg54) 2301249 (forAg33) 2301250 (forAg31) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe."},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13682-5"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201405936"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201809469"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915168"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c02067"},{"key":"e_1_2_7_62_1","unstructured":"\u00a0"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01393E"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06755-4"},{"key":"e_1_2_7_65_1","unstructured":"\u00a0"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202000609"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR07117B"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02165"},{"key":"e_1_2_7_69_1","unstructured":"\u00a0"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.33.8822"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.38.3098"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.1056"},{"key":"e_1_2_7_73_1","unstructured":"\u00a0"},{"key":"e_1_2_7_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/P29930000799"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100007a062"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.472829"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp002676m"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03396J"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00159"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909825"},{"key":"e_1_2_7_81_1","unstructured":"\u00a0"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41050-x"},{"key":"e_1_2_7_83_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314515"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202403464","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,11,28]],"date-time":"2024-11-28T06:44:53Z","timestamp":1732776293000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202403464"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,2]]},"references-count":83,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2024,6,3]]}},"alternative-id":["10.1002\/anie.202403464"],"URL":"https:\/\/doi.org\/10.1002\/anie.202403464","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,5,2]]},"assertion":[{"value":"2024-02-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-05-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202403464"}}