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However, the nature of organic polymers makes the balance between high activity and stability challenging. We demonstrate that the linkage position matters in the design of robust COF photocatalysts with durable high activity without sacrificial reagents. COFs with ortho\u2010 and para\u2010linkages (\n                    <jats:italic>o<\/jats:italic>\n                    \u2010COFs and\n                    <jats:italic>p<\/jats:italic>\n                    \u2010COFs) were constructed by 1,3,5\u2010triformylphloroglucinol with benzene\u2010, pyridine\u2010, pyrazine\u2010orthodiamines and paradiamines. The pyrzaine\u2010containing\n                    <jats:italic>o<\/jats:italic>\n                    \u2010COFs with two pyridinic nitrogen atoms exhibited a H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production rate of 4396\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    together with long\u2010time continuous H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    photosynthesis performance in pure water (48\u2005h), superior to the corresponding\n                    <jats:italic>p<\/jats:italic>\n                    \u2010COFs. A four\u2010step reaction mechanism is proposed by density function calculations. Moreover, the active sites and origin of stability enhancement for\n                    <jats:italic>o<\/jats:italic>\n                    \u2010COFs are clarified. This work provides a simple and effective molecular design strategy in the design of robust COF photocatalysts for artificial H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    photosynthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202404077","type":"journal-article","created":{"date-parts":[[2024,3,17]],"date-time":"2024-03-17T23:45:36Z","timestamp":1710719136000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":158,"title":["Robust Covalent Organic Framework Photocatalysts for H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    Production: Linkage Position Matters"],"prefix":"10.1002","volume":"63","author":[{"given":"Tao","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"De","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Chemical Assessment and Sustainability School of Chemical Science and Engineering Tongji University  Shanghai 200092 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aiguo","family":"Kong","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingying","family":"Zou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Molecular Engineering East China Normal University  Shanghai 200241 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijia","family":"Luo","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Chemical Assessment and Sustainability School of Chemical Science and Engineering Tongji University  Shanghai 200092 P. R. 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China"},{"name":"Australian Institute for Bioengineering and Nanotechnology The University of Queensland  Brisbane Queensland 4072 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,9]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.09.013"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00458H"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c00936"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202103266"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503779"},{"key":"e_1_2_7_7_1","unstructured":"\u00a0"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911609"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0110-6"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003323"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC04236F"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.04.017"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02666"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202328"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09979"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04622"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0398-0"},{"key":"e_1_2_7_19_2","author":"Wang X.","year":"2023","journal-title":"Angew. 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