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Alkaline CO\n                    <jats:sub>2<\/jats:sub>\n                    electrolyzers exhibit high CO\n                    <jats:sub>2<\/jats:sub>\n                    RR activity, low full\u2010cell voltages, and cost\u2010effectiveness. However, the issue of CO\n                    <jats:sub>2<\/jats:sub>\n                    loss caused by (bi)carbonate formation leads to excessive energy consumption, rendering the process economically impractical. In this study, we propose a trilayer polymer electrolyte (TPE) comprising a perforated anion exchange membrane (PAEM) and a bipolar membrane (BPM) to facilitate alkaline CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. This TPE enables the coexistence of high alkalinity near the catalyst surface and the H\n                    <jats:sup>+<\/jats:sup>\n                    flux at the interface between the PAEM and the cation exchange layer (CEL) of the BPM, conditions favoring both CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to multicarbon products and (bi)carbonate removal in KOH\u2010fed membrane electrode assembly (MEA) reactors. As a result, we achieve a Faradaic efficiency (FE) of approximately 46\u2009% for C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    , corresponding to a C\n                    <jats:sub>2+<\/jats:sub>\n                    FE of 64\u2009% at 260\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , with a CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    single\u2010pass conversion (SPC) of approximately 32\u2009% at 140\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u2014nearly 1.3\u2005times the limiting SPC in conventional AEM\u2010MEA electrolyzers. Furthermore, coupling CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction with formaldehyde oxidation reaction (FOR) in the TPE\u2010MEA electrolyzer reduces the full\u2010cell voltage to 2.3\u2005V at 100\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    without compromising the C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    FE.\n                  <\/jats:p>","DOI":"10.1002\/anie.202404110","type":"journal-article","created":{"date-parts":[[2024,6,21]],"date-time":"2024-06-21T09:30:24Z","timestamp":1718962224000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Trilayer Polymer Electrolytes Enable Carbon\u2010Efficient CO\n                    <sub>2<\/sub>\n                    to Multicarbon Product Conversion in Alkaline Electrolyzers"],"prefix":"10.1002","volume":"63","author":[{"given":"Jundong","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuesheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoxiang","family":"Bai","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiying","family":"Deng","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binbin","family":"Pan","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0506-0451","authenticated-orcid":false,"given":"Yanguang","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5336-5183","authenticated-orcid":false,"given":"Yuhang","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 China"},{"name":"Jiangsu Key Laboratory for Advanced Negative Carbon Technologies Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,5]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav3506"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00071J"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301767"},{"key":"e_1_2_7_4_1","volume":"34","author":"Xue H.","year":"2023","journal-title":"Chin. 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