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This simplest gold\u2010alkyne complex has been characterized by single crystal X\u2010ray diffraction, solution and solid\u2010state NMR spectroscopy and periodic DFT. Bonding of HC\u2261CH with [Au(\n                    <jats:bold>L1<\/jats:bold>\n                    )]\n                    <jats:sup>+<\/jats:sup>\n                    comprises both \u03c3\u2010donation and \u03c0\u2010backdonation with additional dispersion interactions within the cavity\u2010shaped phosphine.\n                  <\/jats:p>","DOI":"10.1002\/anie.202404264","type":"journal-article","created":{"date-parts":[[2024,5,3]],"date-time":"2024-05-03T05:51:31Z","timestamp":1714715491000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["A Gold(I)\u2013Acetylene Complex Synthesised using Single\u2010Crystal Reactivity"],"prefix":"10.1002","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0183-2955","authenticated-orcid":false,"given":"Chloe L.","family":"Johnson","sequence":"first","affiliation":[{"name":"Department of Chemistry University of York  York YO10 5DD UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel J.","family":"Storm","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry University of St Andrews, North Haugh  St Andrews KY16 9ST UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4119-9912","authenticated-orcid":false,"given":"M. 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