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In this study, an efficient cascade methanol oxidation reaction is catalyzed by single\u2010Ir\u2010atom catalyst at ultra\u2010low potential (&lt;0.1\u2005V) with the promotion of the thermal and electrochemical integration in a high temperature polymer electrolyte membrane electrolyzer. At the elevated temperature, the electron deficient Ir site with higher methanol affinity could spontaneous catalyze the CH\n                    <jats:sub>3<\/jats:sub>\n                    OH dehydrogenation to CO under the voltage, then the generated CO and H\n                    <jats:sub>2<\/jats:sub>\n                    was electrochemically oxidized to CO\n                    <jats:sub>2<\/jats:sub>\n                    and proton. However, the methanol cannot thermally decompose with the voltage absence, which confirm the indispensable of the coupling of thermal and electrochemical integration for the methanol oxidation. By assembling the methanol oxidation reaction with hydrogen evolution reaction with single\u2010Ir\u2010atom catalysts in the anode chamber, a max hydrogen production rate reaches 18\u2005mol\u2009g\n                    <jats:sub>Ir<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is much greater than that of Ir nanoparticles and commercial Pt\/C. This study also demonstrated the electrochemical methanol oxidation activity of the single atom catalysts, which broadens the renewable energy devices and the catalyst design by an integration concept.\n                  <\/jats:p>","DOI":"10.1002\/anie.202404713","type":"journal-article","created":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T21:58:50Z","timestamp":1714168730000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":57,"title":["Ultra\u2010Low\u2010Potential Methanol Oxidation on Single\u2010Ir\u2010Atom Catalyst"],"prefix":"10.1002","volume":"63","author":[{"given":"Liyuan","family":"Gong","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemo\/Bio-Sensing and Chemometrics College of Chemistry and Chemical Engineering the National Supercomputer Centers in Changsha Advanced Catalytic Engineering Research Center of the Ministry of Education Hunan University  Changsha 410082 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