{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:39:32Z","timestamp":1785890372767,"version":"3.56.0"},"reference-count":125,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2024,10,10]],"date-time":"2024-10-10T00:00:00Z","timestamp":1728518400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100012542","name":"Sichuan Province Science and Technology Support Program","doi-asserted-by":"publisher","award":["2022ZYD0050"],"award-info":[{"award-number":["2022ZYD0050"]}],"id":[{"id":"10.13039\/100012542","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100012542","name":"Sichuan Province Science and Technology Support Program","doi-asserted-by":"publisher","award":["2024NSFSC0285"],"award-info":[{"award-number":["2024NSFSC0285"]}],"id":[{"id":"10.13039\/100012542","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22471177"],"award-info":[{"award-number":["22471177"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004912","name":"Sichuan University","doi-asserted-by":"publisher","award":["YJ2021161"],"award-info":[{"award-number":["YJ2021161"]}],"id":[{"id":"10.13039\/501100004912","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2024,11,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A bisphosphirane\u2010fused anthracene (<jats:bold>5<\/jats:bold>) was prepared by treatment of a sterically encumbered amino phosphorus dichloride (<jats:bold>3<\/jats:bold>) with Mg<jats:bold>A<\/jats:bold>\u2009\u22c5\u2009THF<jats:sub>3<\/jats:sub> (<jats:bold>A<\/jats:bold>=anthracene). X\u2010ray diffraction analysis revealed a pentacyclic framework consisting of <jats:bold>5<\/jats:bold> with two phosphirane rings fused to the anthracene in a <jats:italic>trans<\/jats:italic>\u2010fashion. Compound <jats:bold>5<\/jats:bold> has been shown to be an efficient phosphinidene synthon, readily liberating two transient phosphinidene units for subsequent downstream bond activation via the reductive elimination of anthracene under mild conditions. The formal oxidative addition of H<jats:sub>2<\/jats:sub> and E\u2212H (E=Si, N, P) bonds by the liberated phosphinidene provided diphosphine and substituted phosphines. Furthermore, phosphinidene transfer to alkenes and alkynes smoothly yielded the corresponding phosphiranes and phosphirenes. The mechanism of the H<jats:sub>2<\/jats:sub> activation by <jats:bold>5<\/jats:bold> was investigated by density functional theory (DFT) calculations.<\/jats:p>","DOI":"10.1002\/anie.202405122","type":"journal-article","created":{"date-parts":[[2024,8,1]],"date-time":"2024-08-01T05:14:24Z","timestamp":1722489264000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Aromative Dephosphinidenation of a Bisphosphirane\u2010Fused Anthracene toward E\u2212H (E=H, Si, N and P) Bond Activation"],"prefix":"10.1002","volume":"63","author":[{"given":"Qing","family":"Luo","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemistry &amp; Technology of Ministry of Education College of Chemistry Sichuan University  29 Wangjiang Road 610064 Chengdu P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry &amp; Technology of Ministry of Education College of Chemistry Sichuan University  29 Wangjiang Road 610064 Chengdu P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linlin","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry &amp; Technology of Ministry of Education College of Chemistry Sichuan University  29 Wangjiang Road 610064 Chengdu P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry &amp; Technology of Ministry of Education College of Chemistry Sichuan University  29 Wangjiang Road 610064 Chengdu P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2529-5290","authenticated-orcid":false,"given":"Wei","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry &amp; Technology of Ministry of Education College of Chemistry Sichuan University  29 Wangjiang Road 610064 Chengdu P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,10]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215838"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202215838"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202300078"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214499"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111121"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202111121"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00204"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213749"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11791"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01639"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/B813332H"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.07.007"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr941164z"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207064"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202207064"},{"key":"e_1_2_7_14_1","unstructured":"\u00a0"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.04.015"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.04.001"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04232"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11496"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202400110"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02256"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218587"},{"key":"e_1_2_7_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202218587"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c03302"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703672"},{"key":"e_1_2_7_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201703672"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.10.009"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4072699"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200700483"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja015767l"},{"key":"e_1_2_7_29_1","unstructured":"\u00a0"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00017"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905689"},{"key":"e_1_2_7_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905689"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/b702063p"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200204)2002:7<1127::AID-EJOC1127>3.0.CO;2-X"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00146a006"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198702753"},{"key":"e_1_2_7_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19870990404"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9942944"},{"key":"e_1_2_7_37_1","unstructured":"\u00a0"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11263"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02236"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07959"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06840"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aaz3168"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05464"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10545"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja507922x"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja306902j"},{"key":"e_1_2_7_47_1","unstructured":"\u00a0"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10682"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13080"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00798"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.188501802119"},{"key":"e_1_2_7_52_1","unstructured":"\u00a0"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3OB01525D"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116171"},{"key":"e_1_2_7_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202116171"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00224K"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.06.035"},{"key":"e_1_2_7_57_1","unstructured":"\u00a0"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202301973"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT02802H"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja025522o"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00104a049"},{"key":"e_1_2_7_62_1","unstructured":"\u00a0"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107238"},{"key":"e_1_2_7_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107238"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007543"},{"key":"e_1_2_7_64_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201007543"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202303695"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol901122h"},{"key":"e_1_2_7_67_1","unstructured":"\u00a0"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b04930"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja054885w"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14779"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49042-1"},{"key":"e_1_2_7_72_1","unstructured":"\u00a0"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527829170.ch6"},{"key":"e_1_2_7_74_2","doi-asserted-by":"publisher","DOI":"10.1055\/a-1535-3215"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201801201"},{"key":"e_1_2_7_76_1","unstructured":"For carbene insertion see:"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC05122B"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja411626v"},{"key":"e_1_2_7_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo010277x"},{"key":"e_1_2_7_80_1","unstructured":"\u00a0"},{"key":"e_1_2_7_81_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0153-1"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202300581"},{"key":"e_1_2_7_83_2","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwad169"},{"key":"e_1_2_7_84_1","unstructured":"Deposition numbers 2340090 (for3) 2340091 (for4) 2340092 (for5) 2340093 (for6) 2340094 (for7) 2340095 (for8) 2340096 (for9) 2340097 (for10) 2340098 (for11) 2340099 (for12) and 2340100 (for13) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00104a004"},{"key":"e_1_2_7_86_1","unstructured":"\u00a0"},{"key":"e_1_2_7_87_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja209215a"},{"key":"e_1_2_7_88_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_7_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja053247a"},{"key":"e_1_2_7_90_1","unstructured":"\u00a0"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608324"},{"key":"e_1_2_7_91_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201608324"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja311842r"},{"key":"e_1_2_7_93_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja102913g"},{"key":"e_1_2_7_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja105075h"},{"key":"e_1_2_7_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00924"},{"key":"e_1_2_7_96_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141474"},{"key":"e_1_2_7_97_1","unstructured":"\u00a0"},{"key":"e_1_2_7_98_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402874"},{"key":"e_1_2_7_99_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301042u"},{"key":"e_1_2_7_100_1","unstructured":"\u00a0"},{"key":"e_1_2_7_101_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201604094"},{"key":"e_1_2_7_102_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803938"},{"key":"e_1_2_7_102_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803938"},{"key":"e_1_2_7_103_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402175"},{"key":"e_1_2_7_103_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402175"},{"key":"e_1_2_7_104_1","unstructured":"\u00a0"},{"key":"e_1_2_7_105_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606892"},{"key":"e_1_2_7_105_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606892"},{"key":"e_1_2_7_106_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.3c00295"},{"key":"e_1_2_7_107_2","doi-asserted-by":"publisher","DOI":"10.1021\/om2009974"},{"key":"e_1_2_7_108_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic2026945"},{"key":"e_1_2_7_109_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100137d"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200600444"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-008096518-5.00008-3"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202405122","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,4,4]],"date-time":"2025-04-04T23:59:31Z","timestamp":1743811171000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202405122"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,10]]},"references-count":125,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2024,11,11]]}},"alternative-id":["10.1002\/anie.202405122"],"URL":"https:\/\/doi.org\/10.1002\/anie.202405122","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,10,10]]},"assertion":[{"value":"2024-03-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-10-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202405122"}}