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In this study, we report the synthesis of ultrathin A\/IMC PtPbBi nanosheets (NSs) for boosting hydrogen evolution reaction (HER) and alcohol oxidation reactions. The resulting A\/IMC PtPbBi NSs exhibit a remarkably low overpotential of only 25\u2005mV at 10\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for the HER in an acidic electrolyte, together with outstanding stability for 100\u2005h. In addition, the PtPbBi NSs show high mass activities for methanol oxidation reaction (MOR) and ethanol oxidation reaction (EOR), which are 13.2 and 14.5 times higher than those of commercial Pt\/C, respectively. Density functional theory calculations demonstrate that the synergistic effect of amorphous\/intermetallic components and multimetallic composition facilitate the electron transfer from the catalyst to key intermediates, thus improving the catalytic activity of MOR. This work establishes a novel pathway for the synthesis of heterophase two\u2010dimensional nanomaterials with high electrocatalytic performance across a wide range of electrochemical applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.202405173","type":"journal-article","created":{"date-parts":[[2024,4,16]],"date-time":"2024-04-16T00:13:44Z","timestamp":1713226424000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":69,"title":["Breaking Highly Ordered PtPbBi Intermetallic with Disordered Amorphous Phase for Boosting Electrocatalytic Hydrogen Evolution and Alcohol Oxidation"],"prefix":"10.1002","volume":"63","author":[{"given":"Fukai","family":"Feng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Nuclear Power Safety Technology and Equipment University of Science and Technology Beijing  Beijing 100083 China"},{"name":"School of Materials Science and Engineering University of Science and 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