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However, several reported post\u2010synthetic strategies remain unsatisfactory, considering issues such as damage to the crystallinity of MOFs, presence of impure phases, and high time and energy consumption. In this work, we demonstrate for the first time a novel route for constructing MOF based heterostructures using radiation\u2010induced post\u2010synthesis, highlighting the merits of convenience, ambient conditions, large\u2010scale production, and notable time and energy saving. Specifically, a new HKUST\u20101@Cu<jats:sub>2<\/jats:sub>O heterostructure was successfully synthesized by simply irradiating a methanol solution dispersed of HKUST\u20101 with gamma ray under ambient conditions. The copper source of Cu<jats:sub>2<\/jats:sub>O was directly derived from in situ radiation etching and reduction of the parent HKUST\u20101, without the use of any additional copper reagents. Significantly, the resulting HKUST\u20101@Cu<jats:sub>2<\/jats:sub>O heterostructure exhibits remarkable catalytic performance, with a catalytic rate constant nearly two orders of magnitude higher than that of the parent HKUST\u20101.<\/jats:p>","DOI":"10.1002\/anie.202405213","type":"journal-article","created":{"date-parts":[[2024,4,19]],"date-time":"2024-04-19T03:43:31Z","timestamp":1713498211000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["A MOF@Metal Oxide Heterostructure Induced by Post\u2010Synthetic Gamma\u2010Ray Irradiation for Catalytic Reduction"],"prefix":"10.1002","volume":"63","author":[{"given":"Mingxing","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junchang","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofang","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuanzhi","family":"Mao","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai 201800 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyang","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan","family":"Diwu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhong","family":"Wu","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Applied Physics Chinese Academy of Sciences  Shanghai 201800 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhifang","family":"Chai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1526-1102","authenticated-orcid":false,"given":"Shuao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Medicine of Jiangsu Higher Education Institutions Soochow University  Suzhou 215123 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,24]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35047e"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213946"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1272"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja207077u"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1099006"},{"key":"e_1_2_3_7_1","unstructured":"\u00a0"},{"key":"e_1_2_3_8_2","author":"You Q.","year":"2024","journal-title":"J. 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